Methods of polymerization
作者： Idriss Blakey , Michael Whittaker , Gary M. Day , Tom Davis , Peter Kambouris
DOI:
关键词: Polymer chemistry 、 Chemical engineering 、 Materials science 、 Solid-phase synthesis 、 Substrate (printing) 、 Polymer 、 Raft 、 Polymerization
摘要: The present invention provides improved methods for conducting living/controlled polymerization on polymeric solid supports. allow to occur directly from the non-functionalized surface of a bulk support. In addition, may be re-initiated provide co-polymers. disclosed employ non-nitroxide-based RAFT and ATRP control agents that controlled proceed at relatively low temperatures (<80° C.). Furthermore, these graft polymers with decreased levels “in-growth” also substrate polymers, properties phase synthesis diagnostic applications, which made by methods.
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