Chemical effects of satellites on X-ray emission spectra-I. Observation of chemical effects in Cl Kα spectra
作者： Jun kawai , Kenji Fujisawa , Yohichi Gohshi , Chikatoshi Satoko
DOI: 10.1016/0584-8547(87)80137-4
关键词: Emission spectrum 、 Analytical chemistry 、 Chemistry 、 Fluorescence 、 Chlorine 、 Line (formation) 、 Stereochemistry 、 X-ray 、 Covalent bond 、 Spectral line 、 Spectrometer
摘要: Abstract Fluorescent K α X-ray spectra of Cl were observed with a two-crystal spectrometer equipped Si(111) + analyzer crystals. line shapes appeared asymmetrically smeared due to the presence shake satellites within natural width main lines. Two components, which assigned transitions KM → LM and 2 by X calculations, found numerical deconvolution. The relative intensity parasites-satellites behind lines-was measured for number compounds. Bonding effects n satellites-parasites-of chlorine ( = 1, 2). It was that more covalent compound, weaker parasites become except few
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