An enhanced surface passivation effect in InGaN/GaN disk-in-nanowire light emitting diodes for mitigating Shockley–Read–Hall recombination

作者: Chao Zhao , Tien Khee Ng , Aditya Prabaswara , Michele Conroy , Shafat Jahangir

DOI: 10.1039/C5NR03448E

关键词: X-ray photoelectron spectroscopyOptoelectronicsPassivationNanowireSurface statesQuantum efficiencyMaterials scienceDangling bondLight-emitting diodePhotoluminescence

摘要: We present a detailed study of the effects dangling bond passivation and comparison different sulfide processes on properties InGaN/GaN quantum-disk (Qdisk)-in-nanowire based light emitting diodes (NW-LEDs). Our results demonstrated first organic process for nitride nanowires (NWs). The from Raman spectroscopy, photoluminescence (PL) measurements, X-ray photoelectron spectroscopy (XPS) showed that octadecylthiol (ODT) effectively passivated surface states, altered dynamic charge, thereby recovered band-edge emission. effectiveness with duration was also studied. Moreover, we compared electro-optical performance NW-LEDs at green wavelength before after ODT passivation. have shown Shockley–Read–Hall (SRH) non-radiative recombination can be greatly reduced by ODT, which led to much faster increasing trend quantum efficiency higher peak efficiency. highlighted possibility employing this technique further design produce high NW-lasers.

参考文章(57)
Shuji Nakamura, Gerhard Fasol, The Blue Laser Diode: GaN based Light Emitters and Lasers ,(1997)
S. A. Chevtchenko, M. A. Reshchikov, Q. Fan, X. Ni, Y. T. Moon, A. A. Baski, H. Morkoç, Study of SiNx and SiO2 passivation of GaN surfaces Journal of Applied Physics. ,vol. 101, pp. 113709- ,(2007) , 10.1063/1.2740324
June O Song, Seong-Ju Park, Tae-Yeon Seong, Effects of sulfur passivation on Ti/Al ohmic contacts to n-type GaN using CH3CSNH2 solution Applied Physics Letters. ,vol. 80, pp. 3129- 3131 ,(2002) , 10.1063/1.1475773
Hannah J. Joyce, Patrick Parkinson, Nian Jiang, Callum J. Docherty, Qiang Gao, H. Hoe Tan, Chennupati Jagadish, Laura M. Herz, Michael B. Johnston, Electron mobilities approaching bulk limits in "surface-free" GaAs nanowires Nano Letters. ,vol. 14, pp. 5989- 5994 ,(2014) , 10.1021/NL503043P
Wei Guo, Meng Zhang, Animesh Banerjee, Pallab Bhattacharya, Catalyst-free InGaN/GaN nanowire light emitting diodes grown on (001) silicon by molecular beam epitaxy. Nano Letters. ,vol. 10, pp. 3355- 3359 ,(2010) , 10.1021/NL101027X
Ulrich T. Schwarz, Michael Kneissl, Nitride emitters go nonpolar Physica Status Solidi-rapid Research Letters. ,vol. 1, ,(2007) , 10.1002/PSSR.200750018
Chaw Keong Yong, Keian Noori, Qiang Gao, Hannah J. Joyce, H. Hoe Tan, Chennupati Jagadish, Feliciano Giustino, Michael B. Johnston, Laura M. Herz, Strong carrier lifetime enhancement in GaAs nanowires coated with semiconducting polymer. Nano Letters. ,vol. 12, pp. 6293- 6301 ,(2012) , 10.1021/NL3034027
R. H. Lyddane, R. G. Sachs, E. Teller, On the Polar Vibrations of Alkali Halides Physical Review. ,vol. 59, pp. 673- 676 ,(1941) , 10.1103/PHYSREV.59.673
An-Jye Tzou, Bing-Cheng Lin, Chia-Yu Lee, Da-Wei Lin, Yu-Kuang Liao, Zhen-Yu Li, Gou-Chung Chi, Hao-Chung Kuo, Chun-Yen Chang, Efficiency droop behavior improvement through barrier thickness modification for GaN-on-silicon light-emitting diodes Journal of Photonics for Energy. ,vol. 5, pp. 057604- 057604 ,(2015) , 10.1117/1.JPE.5.057604