Density, Viscosity, and Conductivity of Binary Mixtures of the Ionic Liquid N-(2-Hydroxyethyl)piperazinium Propionate with Water, Methanol, or Ethanol
作者： Qi Cao , Xiaoxing Lu , Xi Wu , Yongsheng Guo , Li Xu
DOI: 10.1021/JE500380X
关键词: Molar volume 、 Analytical chemistry 、 Electrical resistivity and conductivity 、 Ionic liquid 、 Propionate 、 Pitzer equations 、 Inorganic chemistry 、 Chemistry 、 Viscosity 、 Conductivity 、 Methanol
摘要: The densities, viscosities, and electrical conductivities of the binary systems ionic liquid (IL), N-(2-hydroxyethyl)piperazinium propionate ([(OH)2C2pi][C2CO2]), with three protic solvents (water, methanol, or ethanol) were measured in IL concentration range from (0.05 to 3.00) mol·kg–1 at different temperatures T = (293.15 323.15) K atmospheric pressure p 0.1 MPa. dependences apparent molar volume, viscosity, conductivity mixtures correlated by Pitzer equation, Jones–Dole Casteel–Amis respectively. It is observed that both density viscosity increase elevated decreased temperature. a given increases temperature, while temperature changes clearly against concentration, maximum value can be observed. results correlations present help for ...
acs.org
sci-hub.se 参考文章(37)
Donald G. Archer, Peiming Wang, The Dielectric Constant of Water and Debye‐Hückel Limiting Law Slopes Journal of Physical and Chemical Reference Data. ,vol. 19, pp. 371- 411 ,(1990) , 10.1063/1.555853
Felipe Hernández-Luis, Raquel Rodríguez-Raposo, Héctor R. Galleguillos, Jaime W. Morales, Activity Coefficients of NaCl in Aqueous Mixtures with High Relative Permittivity Cosolvent: Ethylene Carbonate + Water at 298.15 K Journal of Chemical & Engineering Data. ,vol. 55, pp. 3349- 3355 ,(2010) , 10.1021/JE100121U
Daniel J. Bradley, Kenneth S. Pitzer, Thermodynamics of electrolytes. 12. Dielectric properties of water and Debye-Hueckel parameters to 350.degree.C and 1 kbar The Journal of Physical Chemistry. ,vol. 83, pp. 1599- 1603 ,(1979) , 10.1021/J100475A009
George Ritzoulis, Doukeni Missopolinou, Stauroula Doulami, Costas Panayiotou, Relative Permittivities, Densities, Refractive Indices and Ultrasound Velocities of the Binary Systems of γ-Butyrolactone with Methanol, Ethanol, 1-Butanol, and 1-Octanol Journal of Chemical & Engineering Data. ,vol. 45, pp. 636- 641 ,(2000) , 10.1021/JE990226L
Pankaj Attri, Pannuru Venkatesu, Anil Kumar, Activity and stability of α-chymotrypsin in biocompatible ionic liquids: enzyme refolding by triethyl ammonium acetate Phys. Chem. Chem. Phys.. ,vol. 13, pp. 2788- 2796 ,(2011) , 10.1039/C0CP01291B
Jason P. Hallett, Tom Welton, Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Chemical Reviews. ,vol. 99, pp. 2071- 2083 ,(1999) , 10.1021/CR1003248
Zhang, Han, Viscosity and Density of Water + Sodium Chloride + Potassium Chloride Solutions at 298.15 K Journal of Chemical & Engineering Data. ,vol. 41, pp. 516- 520 ,(1996) , 10.1021/JE9501402
Suojiang Zhang, Xian Li, Huiping Chen, Junfeng Wang, Jianmin Zhang, Milin Zhang, Determination of Physical Properties for the Binary System of 1-Ethyl-3-methylimidazolium Tetrafluoroborate + H2O Journal of Chemical & Engineering Data. ,vol. 49, pp. 760- 764 ,(2004) , 10.1021/JE030191W
Víctor H. Alvarez, Silvana Mattedi, Manuel Martin-Pastor, Martin Aznar, Miguel Iglesias, Thermophysical properties of binary mixtures of {ionic liquid 2-hydroxy ethylammonium acetate + (water, methanol, or ethanol)} The Journal of Chemical Thermodynamics. ,vol. 43, pp. 997- 1010 ,(2011) , 10.1016/J.JCT.2011.01.014
Xiao Liang Yuan, Suo Jiang Zhang, Xing Mei Lu, Hydroxyl Ammonium Ionic Liquids: Synthesis, Properties, and Solubility of SO2 Journal of Chemical & Engineering Data. ,vol. 52, pp. 596- 599 ,(2007) , 10.1021/JE060479W