Density and Viscosity Measurements for Binary Mixtures of 1-Ethyl-3-methylimidazolium Tetrafluoroborate ([Emim][BF4]) with Dimethylacetamide, Dimethylformamide, and Dimethyl Sulfoxide
作者： Xian-Heng Fan , Yan-Ping Chen , Chie-Shaan Su
关键词:
摘要: The density and viscosity data of three binary liquid mixtures containing the ionic (IL) 1-ethyl-3-methylimidazolium tetrafluoroborate organic solvents, dimethylacetamide (DMAC), dimethylformamide (DMF), dimethyl sulfoxide (DMSO) were obtained under atmospheric pressure, at temperatures 303.15 to 333.15 K over entire composition range. A vibrating-tube digital meter a capillary viscometer used for measurements, respectively. Excess molar volumes (VE) deviations (Δη) mixture system calculated from experimental satisfactorily fitted with Redlich–Kister equation. Adding DMAC, DMF, DMSO led negative values VE Δη. This finding revealed that packing constituents was more efficient, anion–cation interaction IL decreased in mixtures. sequences Δη this study are also discussed using interm...
acs.org
ntu.edu.tw
sci-hub.se 参考文章(29)
S. Govardhana Rao, T. Madhu Mohan, T. Vijaya Krishna, K. Narendra, B. Subba Rao, Thermophysical properties of 1-butyl-3-methylimidazolium tetrafluoroborate and N-methyl-2-pyrrolidinone as a function of temperature Journal of Molecular Liquids. ,vol. 211, pp. 1009- 1017 ,(2015) , 10.1016/J.MOLLIQ.2015.08.019
Changsheng Yang, Guanghu He, Yifu He, Peisheng Ma, Densities and Viscosities of N,N-Dimethylformamide + N-Methyl-2-pyrrolidinone and + Dimethyl Sulfoxide in the Temperature Range (303.15 to 353.15) K Journal of Chemical & Engineering Data. ,vol. 53, pp. 1639- 1642 ,(2008) , 10.1021/JE800138B
Michel Armand, Frank Endres, Douglas R. MacFarlane, Hiroyuki Ohno, Bruno Scrosati, Ionic-liquid materials for the electrochemical challenges of the future. Nature Materials. ,vol. 8, pp. 621- 629 ,(2009) , 10.1038/NMAT2448
T. Kavitha, T. Vasantha, P. Venkatesu, R.S. Rama Devi, T. Hofman, Thermophysical properties for the mixed solvents of N-methyl-2-pyrrolidone with some of the imidazolium-based ionic liquids Journal of Molecular Liquids. ,vol. 198, pp. 11- 20 ,(2014) , 10.1016/J.MOLLIQ.2014.07.002
S. Bhagour, S. Solanki, N. Hooda, D. Sharma, V.K. Sharma, Thermodynamic properties of binary mixtures of the ionic liquid [emim][BF4] with acetone and dimethylsulphoxide The Journal of Chemical Thermodynamics. ,vol. 60, pp. 76- 86 ,(2013) , 10.1016/J.JCT.2013.01.010
Mojtaba Shamsipur, Ali Akbar Miran Beigi, Mohammad Teymouri, Sayed Mahdi Pourmortazavi, Mohsen Irandoust, Physical and electrochemical properties of ionic liquids 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium trifluoromethanesulfonate and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide Journal of Molecular Liquids. ,vol. 157, pp. 43- 50 ,(2010) , 10.1016/J.MOLLIQ.2010.08.005
Jason A. Widegren, Eric M. Saurer, Kenneth N. Marsh, Joseph W. Magee, Electrolytic conductivity of four imidazolium-based room-temperature ionic liquids and the effect of a water impurity The Journal of Chemical Thermodynamics. ,vol. 37, pp. 569- 575 ,(2005) , 10.1016/J.JCT.2005.04.009
Feng Qi, Haijun Wang, Application of Prigogine–Flory–Patterson theory to excess molar volume of mixtures of 1-butyl-3-methylimidazolium ionic liquids with N -methyl-2-pyrrolidinone The Journal of Chemical Thermodynamics. ,vol. 41, pp. 265- 272 ,(2009) , 10.1016/J.JCT.2008.09.003
S. L. Oswal, N. B. Patel, Speed of Sound, Isentropic Compressibility, Viscosity, and Excess Volume of Binary Mixtures. 2. Alkanenitriles + Dimethylformamide, + Dimethylacetamide, and + Dimethyl Sulfoxide Journal of Chemical & Engineering Data. ,vol. 40, pp. 845- 849 ,(1995) , 10.1021/JE00020A024
José S. Torrecilla, Tatiana Rafione, Julián García, Francisco Rodríguez, Effect of Relative Humidity of Air on Density, Apparent Molar Volume, Viscosity, Surface Tension, and Water Content of 1-Ethyl-3-methylimidazolium Ethylsulfate Ionic Liquid Journal of Chemical & Engineering Data. ,vol. 53, pp. 923- 928 ,(2008) , 10.1021/JE700523B