Thermophysical properties for the mixed solvents of N-methyl-2-pyrrolidone with some of the imidazolium-based ionic liquids
作者： T. Kavitha , T. Vasantha , P. Venkatesu , R.S. Rama Devi , T. Hofman
DOI: 10.1016/J.MOLLIQ.2014.07.002
关键词: N-Methyl-2-pyrrolidone 、 Viscosity 、 Ionic liquid 、 Physical chemistry 、 Chloride 、 Inorganic chemistry 、 Tetrafluoroborate 、 Intermolecular force 、 Molar volume 、 Chemistry 、 Molecule
摘要: Abstract This work presents the thermophysical properties and structure of N-methyl-2-pyrrolidone (NMP) in binary mixtures with 1-alkyl-3-methyl imidazolium cation [amim]+ different anions (chloride, methyl sulfate tetrafluoroborate) ionic liquids (ILs). A comprehensive set such as densities (ρ), ultrasonic sound velocities (u) viscosities (η) have been measured at temperature range from 298.15 to 313.15 K over whole concentration ILs under atmospheric pressure. The used for present study included 1-ethyl-3-methylimidazolium methylsulfate [Emim][MeSO4], 1-butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF4], 1-ethyl-3-methyl chloride [Emim][Cl] [Bmim][Cl] family ILs. From these experimental data, excess molar volume (VE), deviation isentropic compressibility (Δκs) viscosity (Δη) were calculated adequately correlated by using Redlich–Kister polynomial equation. data interpreted on basis intermolecular interactions structural effects between like unlike molecules upon mixing.
sci-hub.se 参考文章(51)
Michael Freemantle, An Introduction to Ionic Liquids ,(2021)
Robin D Rogers, Kenneth R Seddon, Ionic Liquids--Solvents of the Future? Science. ,vol. 302, pp. 792- 793 ,(2003) , 10.1126/SCIENCE.1090313
Varadhi Govinda, P. Madhusudhana Reddy, Indra Bahadur, Pankaj Attri, P. Venkatesu, P. Venkateswarlu, Effect of anion variation on the thermophysical properties of triethylammonium based protic ionic liquids with polar solvent Thermochimica Acta. ,vol. 556, pp. 75- 88 ,(2013) , 10.1016/J.TCA.2013.02.002
Ibrahim Bou Malham, Mireille Turmine, Viscosities and refractive indices of binary mixtures of 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-2,3-dimethylimidazolium tetrafluoroborate with water at 298K The Journal of Chemical Thermodynamics. ,vol. 40, pp. 718- 723 ,(2008) , 10.1016/J.JCT.2007.10.002
Allan N. Soriano, Bonifacio T. Doma, Meng-Hui Li, Measurements of the density and refractive index for 1-n-butyl-3-methylimidazolium-based ionic liquids The Journal of Chemical Thermodynamics. ,vol. 41, pp. 301- 307 ,(2009) , 10.1016/J.JCT.2008.08.010
Pankaj Attri, Ku Youn. Baik, Pannuru Venkatesu, In Tae Kim, Eun Ha Choi, Influence of Hydroxyl Group Position and Temperature on Thermophysical Properties of Tetraalkylammonium Hydroxide Ionic Liquids with Alcohols PLoS ONE. ,vol. 9, pp. e86530- ,(2014) , 10.1371/JOURNAL.PONE.0086530
Mengyin Hou, Yingjie Xu, Yajuan Han, Bin Chen, Wenxia Zhang, Qinghua Ye, Jinzhi Sun, Thermodynamic properties of aqueous solutions of two ammonium-based protic ionic liquids at 298.15 K Journal of Molecular Liquids. ,vol. 178, pp. 149- 155 ,(2013) , 10.1016/J.MOLLIQ.2012.11.030
Changsheng Yang, Guanghu He, Yifu He, Peisheng Ma, Densities and Viscosities of N,N-Dimethylformamide + N-Methyl-2-pyrrolidinone and + Dimethyl Sulfoxide in the Temperature Range (303.15 to 353.15) K Journal of Chemical & Engineering Data. ,vol. 53, pp. 1639- 1642 ,(2008) , 10.1021/JE800138B
P. Gnana Kumari, P. Venkatesu, M.V. Prabhakara Rao, Ming-Jer Lee, Ho-mu Lin, Excess molar volumes and ultrasonic studies of N-methyl-2-pyrrolidone with ketones at T=303.15K The Journal of Chemical Thermodynamics. ,vol. 41, pp. 586- 590 ,(2009) , 10.1016/J.JCT.2009.01.006
T. Kavitha, Pankaj Attri, Pannuru Venkatesu, R.S. Rama Devi, T. Hofman, Temperature dependence measurements and molecular interactions for ammonium ionic liquid with N-methyl-2-pyrrolidone The Journal of Chemical Thermodynamics. ,vol. 54, pp. 223- 237 ,(2012) , 10.1016/J.JCT.2012.03.034