Characteristic of cold sprayed catalytic coating for hydrogen production through fuel reforming

作者: Feng Wang , Dingwen Zhang , Shiwei Zheng , Bo Qi

DOI: 10.1016/J.IJHYDENE.2009.12.087

关键词: Filamentous carbonGas dynamic cold sprayHydrogen productionSteam reformingMetallurgyCoatingChemical engineeringNon-blocking I/OCatalysisMaterials scienceScanning electron microscope

摘要: Cold spray was employed as a novel method to prepare NiO/Al 2 O 3 primary steam reforming catalyst coating for hydrogen production. The microstructure characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) before after reactions. catalytic performance examined through methane (SRM) in microreactor. Results showed that successfully deposited on the stainless steel substrate by cold spray. thickness of about 50 μm. It presented rough surface porous structure. Since temperature process is low, no phase changes occurred during deposition. However particle size became smaller compared with feedstock due its smashing. found cold-sprayed active SRM at high space velocity although filamentous carbon formed surface. After reaction there obvious peeling off indicating good bonding between substrate.

参考文章(37)
Denis Candusso, Fabien Harel, A De Bernardinis, X Francois, MC Péra, D Hissel, P Schott, G Coquery, J-M Kauffmann, Characterisation and modelling of a 5 kW PEMFC for transportation applications International Journal of Hydrogen Energy. ,vol. 31, pp. 1019- 1030 ,(2006) , 10.1016/J.IJHYDENE.2005.11.010
A DEHKORDI, M MEMARI, Compartment model for steam reforming of methane in a membrane-assisted bubbling fluidized-bed reactor International Journal of Hydrogen Energy. ,vol. 34, pp. 1275- 1291 ,(2009) , 10.1016/J.IJHYDENE.2008.11.076
M DEFALCO, L DIPAOLA, L MARRELLI, Heat transfer and hydrogen permeability in modelling industrial membrane reactors for methane steam reforming International Journal of Hydrogen Energy. ,vol. 32, pp. 2902- 2913 ,(2007) , 10.1016/J.IJHYDENE.2007.04.014
Jeong Gil Seo, Min Hye Youn, Sunyoung Park, Jin Suk Chung, In Kyu Song, Hydrogen production by steam reforming of liquefied natural gas (LNG) over Ni/Al2O3–ZrO2 xerogel catalysts: Effect of calcination temperature of Al2O3–ZrO2 xerogel supports International Journal of Hydrogen Energy. ,vol. 34, pp. 3755- 3763 ,(2009) , 10.1016/J.IJHYDENE.2009.03.030
S. Assabumrungrat, S. Charoenseri, N. Laosiripojana, W. Kiatkittipong, P. Praserthdam, Effect of oxygen addition on catalytic performance of Ni/SiO2·MgO toward carbon dioxide reforming of methane under periodic operation International Journal of Hydrogen Energy. ,vol. 34, pp. 6211- 6220 ,(2009) , 10.1016/J.IJHYDENE.2009.05.128
Sergei Vladimirovich Klinkov, Vladimir Fedorovich Kosarev, Martin Rein, Cold spray deposition : Significance of particle impact phenomena Aerospace Science and Technology. ,vol. 9, pp. 582- 591 ,(2005) , 10.1016/J.AST.2005.03.005
Young-Jun Sohn, Gu-Gon Park, Tae-Hyun Yang, Young-Gi Yoon, Won-Yong Lee, Sung-Dae Yim, Chang-Soo Kim, Operating characteristics of an air-cooling PEMFC for portable applications Journal of Power Sources. ,vol. 145, pp. 604- 609 ,(2005) , 10.1016/J.JPOWSOUR.2005.02.062
Min Hye Youn, Jeong Gil Seo, Kyung Min Cho, Sunyoung Park, Dong Ryul Park, Ji Chul Jung, In Kyu Song, Hydrogen production by auto-thermal reforming of ethanol over nickel catalysts supported on Ce-modified mesoporous zirconia: Effect of Ce/Zr molar ratio International Journal of Hydrogen Energy. ,vol. 33, pp. 5052- 5059 ,(2008) , 10.1016/J.IJHYDENE.2008.07.084
Jeong Gil Seo, Min Hye Youn, Dong Ryul Park, Insung Nam, In Kyu Song, Hydrogen production by steam reforming of liquefied natural gas (LNG) over Ni―Al2O3 catalysts prepared by a sequential precipitation method: Effect of precipitation agent International Journal of Hydrogen Energy. ,vol. 34, pp. 8053- 8060 ,(2009) , 10.1016/J.IJHYDENE.2009.08.020