Compartment model for steam reforming of methane in a membrane-assisted bubbling fluidized-bed reactor

作者: A DEHKORDI , M MEMARI

DOI: 10.1016/J.IJHYDENE.2008.11.076

关键词: Fluidized bedMembrane reactorHydrogen productionMechanicsIsothermal processHydrogenSteam reformingAdiabatic processMethaneChemistry

摘要: Abstract A compartment model was developed to describe the flow pattern of gas within dense zone a membrane-assisted fluidized-bed reactor (MAFBR), in bubbling mode operation for steam reforming methane both with (adiabatic) and without (isothermal) entering oxygen. Considering such using experimental data reported elsewhere [Roy S, Pruden BB, Adris AM, Grace JR, Lim CJ. Fluidized-bed oxygen input. Chem Eng Sci 1999; 54:2095–2102.], parameters (i.e., number compartments bubble emulsion phases) were determined fair agreements obtained between predictions data. The utilized behavior an industrial scale adiabatic isothermal MAFBR. Moreover, influences various operating design as steam-to-methane ratio (SMR), oxygen-to-methane (OMR), temperature pressure, hydrogen membrane tubes on performance capability MAFBR investigated. Furthermore, optimized subject constraints, including 1 ≤ SMR ≤ 4 500 ≤ T ≤ 1250 K, regime.

参考文章(56)
Joseph Schwartz, Hankwon Lim, Raymond Drnevich, INTEGRATED CERAMIC MEMBRANE SYSTEM FOR HYDROGEN PRODUCTION Proc. 2000 Hydrogen Program Review, San Ramon, CA (US), 05/09/2000--05/11/2000. ,(2000) , 10.2172/984651
Marcello De Falco, Pd-based membrane steam reformers: A simulation study of reactor performance International Journal of Hydrogen Energy. ,vol. 33, pp. 3036- 3040 ,(2008) , 10.1016/J.IJHYDENE.2008.03.006
Don Wesley Green, James O Maloney, Robert Howard Perry, Perry's Chemical Engineers' Handbook ,(2007)
J.N. Theron, M.E. Dry, E. van Steen, J.C.Q. Fletcher, Internal and external transport effects during the oxidative reforming of methane on a commercial steam reforming catalyst Studies in Surface Science and Catalysis. ,vol. 107, pp. 455- 460 ,(1997) , 10.1016/S0167-2991(97)80376-X
A. M. Adris, S. S. E. H. Elnashaie, R. Hughes, A fluidized bed membrane reactor for the steam reforming of methane Canadian Journal of Chemical Engineering. ,vol. 69, pp. 1061- 1070 ,(1991) , 10.1002/CJCE.5450690504
Fausto Gallucci, Antonio Comite, Gustavo Capannelli, Angelo Basile, Steam Reforming of Methane in a Membrane Reactor: An Industrial Case Study Industrial & Engineering Chemistry Research. ,vol. 45, pp. 2994- 3000 ,(2006) , 10.1021/IE058063J
W. Yu, T. Ohmori, T. Yamamoto, A. Endo, M. Nakaiwa, N. Itoh, Optimal design and operation of methane steam reforming in a porous ceramic membrane reactor for hydrogen production Chemical Engineering Science. ,vol. 62, pp. 5627- 5631 ,(2007) , 10.1016/J.CES.2007.03.005
Calvin H Bartholomew, Mechanisms of catalyst deactivation Applied Catalysis A-general. ,vol. 212, pp. 17- 60 ,(2001) , 10.1016/S0926-860X(00)00843-7
M DEFALCO, L DIPAOLA, L MARRELLI, Heat transfer and hydrogen permeability in modelling industrial membrane reactors for methane steam reforming International Journal of Hydrogen Energy. ,vol. 32, pp. 2902- 2913 ,(2007) , 10.1016/J.IJHYDENE.2007.04.014