Femtochemistry of the liquid phase laser-induced harpoon reaction between Cl2 and Xe. Observation of bond formation in real time
作者： R. Zadoyan , V.A. Apkarian
DOI: 10.1016/0009-2614(93)80171-K
关键词: Femtochemistry 、 Atomic physics 、 Xenon 、 Intermediate state 、 Triatomic molecule 、 Dissociation (chemistry) 、 Harpoon reaction 、 Radiative transfer 、 Halogen 、 Chemistry
摘要: Abstract The liquid phase, two-photon induced intermolecular charge transfer transition, Cl2 + Xe 2hv → Xe+Cl−2, in which the photon is resonant with dissociative Cl2(1Πu) intermediate state, shown to proceed on a time scale shorter than 100 fs. process therefore classified as coherent, cooperative absorption. subsequent evolution of harpoon reaction, Xe+Cl−2 Xe+Cl− Cl, further proceeds form Xe+2Cl−, followed by stimulating radiative dissociation Xe+Cl−. While formation cannot be temporally resolved, triatomic bond forms 330
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