Thermal, structural and optical investigation of Cu-doped ZnO nanoparticles
作者： Maruthanayagam Jay Chithra , Kuppusamy Pushpanathan
DOI: 10.1142/S0217984916504066
关键词: Analytical chemistry 、 Doping 、 Wurtzite crystal structure 、 Crystallite 、 Dopant 、 Materials science 、 Band gap 、 Scanning electron microscope 、 Magnetic semiconductor 、 Transmission electron microscopy
摘要: Well-dispersed undoped and copper-doped zinc oxide nanoparticles (Zn1−xCuxO, x = 0, 1, 5 10 wt.%) have been synthesized by precipitation method at room temperature. X-ray diffraction data revealed that the are in phase pure wurtzite structure crystallite size increases from 24 nm to 36 with increase dopant concentration. The optical band gap was found decrease increasing concentration, which clearly indicates blue shift. High-resolution scanning electron microscope image shows samples consist of an assembly nanopetals. Transmission also confirmed average particle 20–50 nm. Energy-dispersive spectrum prepared free impurities. Photoluminescence spectra exposed copper ions doped into lattice positions ZnO. A simultaneous differential calorimeter/thermogravimetric analysis combination used study variations.
harvard.edu
sci-hub.se 参考文章(41)
Ozlem Altintas Yildirim, Yuzi Liu, Amanda K. Petford-Long, Synthesis of uniformly distributed single- and double-sided zinc oxide (ZnO) nanocombs Journal of Crystal Growth. ,vol. 430, pp. 34- 40 ,(2015) , 10.1016/J.JCRYSGRO.2015.08.007
N. Tahir, S.T. Hussain, M. Usman, S.K. Hasanain, A. Mumtaz, Effect of vanadium doping on structural, magnetic and optical properties of ZnO nanoparticles Applied Surface Science. ,vol. 255, pp. 8506- 8510 ,(2009) , 10.1016/J.APSUSC.2009.06.003
M. Jay Chithra, M. Sathya, K. Pushpanathan, Effect of pH on Crystal Size and Photoluminescence Property of ZnO Nanoparticles Prepared by Chemical Precipitation Method Acta Metallurgica Sinica (English Letters). ,vol. 28, pp. 394- 404 ,(2015) , 10.1007/S40195-015-0218-8
Qing Ma, D. Bruce Buchholz, Robert P. H. Chang, Local structures of copper-doped ZnO films Physical Review B. ,vol. 78, pp. 214429- ,(2008) , 10.1103/PHYSREVB.78.214429
Özlem Altıntaş Yıldırım, Caner Durucan, None, Effect of precipitation temperature and organic additives on size and morphology of ZnO nanoparticles Journal of Materials Research. ,vol. 27, pp. 1452- 1461 ,(2012) , 10.1557/JMR.2012.58
ShaoMin Zhou, LiSheng Liu, ShiYun Lou, YongQiang Wang, XiLiang Chen, HongLei Yuan, YaoMing Hao, RuiJian Yuan, Ning Li, None, Room-temperature ferromagnetism of diamagnetically-doped ZnO aligned nanorods fabricated by vapor reaction Applied Physics A. ,vol. 102, pp. 367- 371 ,(2011) , 10.1007/S00339-010-6011-7
D. B. Buchholz, R. P. H. Chang, J.-Y. Song, J. B. Ketterson, Room-temperature ferromagnetism in Cu-doped ZnO thin films Applied Physics Letters. ,vol. 87, pp. 082504- ,(2005) , 10.1063/1.2032588
B. Donkova, D. Dimitrov, M. Kostadinov, E. Mitkova, D. Mehandjiev, Catalytic and photocatalytic activity of lightly doped catalysts M:ZnO (M = Cu, Mn) Materials Chemistry and Physics. ,vol. 123, pp. 563- 568 ,(2010) , 10.1016/J.MATCHEMPHYS.2010.05.015
M.T. Mohammad, A.A. Hashim, M.H. Al-Maamory, Highly conductive and transparent ZnO thin films prepared by spray pyrolysis technique Materials Chemistry and Physics. ,vol. 99, pp. 382- 387 ,(2006) , 10.1016/J.MATCHEMPHYS.2005.11.009
Hua-Wei Zhang, Zhi-Ren Wei, Zhi-Qiang Li, Guo-Yi Dong, Room-temperature ferromagnetism in Fe-doped, Fe- and Cu-codoped ZnO diluted magnetic semiconductor Materials Letters. ,vol. 61, pp. 3605- 3607 ,(2007) , 10.1016/J.MATLET.2006.11.139