Relative modulus-relative density relationships in low density polymer-clay nanocomposite foams

作者: Oana M. Istrate , Biqiong Chen

DOI: 10.1039/C0SM01052A

关键词: Scanning electron microscopeComposite materialPorosityRelative densityPolymer clayModulusPolymerPolyurethaneMaterials scienceNanocomposite

摘要: Polymer–clay nanocomposite (PCN) foams represent an important class of new materials in structural engineering, biomedical fields and packaging. This paper reports the relative modulus–relative density relationship, a crucial correlation cellular solids, for low-density PCN foams. Polyurethane (PU)–natural clay with porosity 97% were used studies such relationship. The foam structures characterised by Scanning Electron Microscopy X-ray Micro-Computed Tomography modulus was obtained from compressive testing. It found relationship porosities higher than 95% closely followed normalised Gibson–Ashby models open cells closed cells, case PU–clay geometric constant C1 determined to be approximately 0.45–0.88 well-established model conventional open-cell foams, namely Ef/Es = C1(ρf/ρs)2 where E ρ refer subscripts f s stand solid. effects clay, content mixing sequence on cell structure, physical mechanical properties polymer also discussed.

参考文章(71)
Zhiqiang Liu, M. G. Scanlon, Scaling Young's modulus of cellular solids Journal of Materials Science Letters. ,vol. 22, pp. 547- 548 ,(2003) , 10.1023/A:1022950706432
A Cunningham, N. C. Hilyard, Low density cellular plastics : physical basis of behaviour Chapman & Hall. ,(1994)
A. J. Kinloch, A. C. Taylor, Mechanical and fracture properties of epoxy/inorganic micro- and nano-composites Journal of Materials Science Letters. ,vol. 22, pp. 1439- 1441 ,(2003) , 10.1023/A:1025719715808
Lorna J. Gibson, Michael F. Ashby, Cellular Solids: Structure and Properties ,(1988)
Ebru Günister, İpek Çobanoğlu, Sevim İşçi, The effect of polyurethane on NaMt and ONaMt dispersions Progress in Organic Coatings. ,vol. 65, pp. 357- 361 ,(2009) , 10.1016/J.PORGCOAT.2009.02.005
Biqiong Chen, Julian RG Evans, X-ray diffraction studies and phase volume determinations in poly(ethylene glycol)-montmorillonite nanocomposites Polymer International. ,vol. 54, pp. 807- 813 ,(2005) , 10.1002/PI.1774