Structural changes of B2O3 through the liquid-glass transition range: A Raman-scattering study.
作者： A. K. Hassan , L. M. Torell , L. Börjesson , H. Doweidar
DOI: 10.1103/PHYSREVB.45.12797
关键词: Inorganic compound 、 Spectral line 、 Raman scattering 、 Range (particle radiation) 、 Molecular physics 、 Planar 、 Supercooling 、 Materials science 、 Glass transition 、 Nuclear magnetic resonance 、 Liquid state
摘要: Raman scattering of B 2 O 3 has been performed from room temperature to 1273 K study structural changes as the glass transforms into melt via supercooled regime. It is found that a model containing threefold six-member planar boroxol rings and chains BO triangles can explain experimental spectra. From behavior internal vibrations triangles, we conclude these molecular units do not change significantly increases whereas connectivity strongly affected
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