Surface segregation kinetics in binary alloys

作者: A.D. Brailsford

DOI: 10.1016/0039-6028(80)90014-X

关键词: KineticsSequenceBinary numberNonlinear systemEnrichment ratioSurface (mathematics)ThermodynamicsLinear equationIntegral equationChemistry

摘要: Abstract An integral equation describing the kinetics of surface segregation in a binary alloys is derived. Solution this yields well-known McLean form for when enrichment ratio independent segregant concentration. In other cases nonlinear and must be solved by numerical techniques general. However, here, an alternative approximate analytical scheme developed which entails only solution sequence linear equations. This method used to expose qualitative features effect concentration-dependent upon kinetics. The practical utility approach also established analysis real system. results given agree with those found prior workers using methods.

参考文章(12)
Friedrich Lösch, B. G. Teubner Verlagsgesellschaft (Stuttgart)., McGraw-Hill Publishing Company, Tables of Higher Functions ,(1960)
W.R. Tyson, Kinetics of temper embrittlement Acta Metallurgica. ,vol. 26, pp. 1471- 1478 ,(1978) , 10.1016/0001-6160(78)90162-1
W. H. Reinmuth, DIFFUSION TO A PLANE WITH LANGMUIRIAN ADSORPTION The Journal of Physical Chemistry. ,vol. 65, pp. 473- 476 ,(1961) , 10.1021/J100821A021
H. R. Tipler, D. McLean, Influence of Interface Energy on Creep Rupture Metal Science Journal. ,vol. 4, pp. 103- 107 ,(1970) , 10.1179/030634570790444176
G. Rowlands, D. P. Woodruff, The kinetics of surface and grain boundary segregation in binary and ternary systems Philosophical Magazine. ,vol. 40, pp. 459- 476 ,(1979) , 10.1080/01418617908234852
J BURTON, Surface segregation in alloys Journal of Catalysis. ,vol. 37, pp. 106- 113 ,(1975) , 10.1016/0021-9517(75)90138-4
D. McLean, A. Maradudin, Grain Boundaries in Metals Physics Today. ,vol. 11, pp. 35- 36 ,(1958) , 10.1063/1.3062658
D.A. Mervyn, R.J. Baird, P. Wynblatt, Surface segregation in a Ni-1 at% Pd alloy Surface Science. ,vol. 82, pp. 79- 92 ,(1979) , 10.1016/0039-6028(79)90319-4
Colin Lea, M. P. Seah, Kinetics of surface segregation Philosophical Magazine. ,vol. 35, pp. 213- 228 ,(1977) , 10.1080/14786437708235984