Microwave Spectrum, Barrier to Internal Rotation, and Dipole Moment of Cis‐Crotononitrile
作者： Robert A. Beaudet
DOI: 10.1063/1.1733539
关键词: Transition dipole moment 、 Chemistry 、 Quantum tunnelling 、 Dipole 、 Moment (physics) 、 Microwave 、 Magnetic dipole 、 Molecular physics 、 Quantum electrodynamics 、 Rectangular potential barrier 、 Bond dipole moment 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: The microwave spectrum of cis‐CH3CH=CHCN has been measured and assigned in the region 8–34 kMc/sec. transitions were split by tunneling methyl group through potential barrier to internal rotation. From these separations was determined as 1400 cal/mole. total dipole moment is 4.08 D.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(9)
Robert A. Beaudet, E. Bright Wilson, Microwave Spectrum and Barrier to Internal Rotation ofcis‐1‐Fluoropropylene The Journal of Chemical Physics. ,vol. 37, pp. 1133- 1138 ,(1962) , 10.1063/1.1733225
Victor W. Laurie, Note on the Determination of Molecular Structure from Spectroscopic Data Journal of Chemical Physics. ,vol. 28, pp. 704- 706 ,(1958) , 10.1063/1.1744218
Dudley R. Herschbach, Calculation of Energy Levels for Internal Torsion and Over‐All Rotation. III The Journal of Chemical Physics. ,vol. 31, pp. 91- 108 ,(1959) , 10.1063/1.1730343
David R. Lide, Daniel Christensen, Molecular Structure of Propylene Journal of Chemical Physics. ,vol. 35, pp. 1374- 1378 ,(1961) , 10.1063/1.1732055
C. C. Costain, B. P. Stoicheff, Microwave Spectrum, Molecular Structure of Vinyl Cyanide and a Summary of CC, CH Bond Lengths in Simple Molecules The Journal of Chemical Physics. ,vol. 30, pp. 777- 782 ,(1959) , 10.1063/1.1730044
David R. Lide, D. E. Mann, Microwave Spectra of Molecules Exhibiting Internal Rotation. I. Propylene The Journal of Chemical Physics. ,vol. 27, pp. 868- 873 ,(1957) , 10.1063/1.1743867
Seymour Siegel, Microwave Spectrum and Barrier to Internal Rotation for Trans‐Fluoro‐Propylene The Journal of Chemical Physics. ,vol. 27, pp. 989- 990 ,(1957) , 10.1063/1.1743920
Victor W. Laurie, Microwave Spectrum of trans‐Crotononitrile Journal of Chemical Physics. ,vol. 32, pp. 1588- 1589 ,(1960) , 10.1063/1.1730981
Louis Pierce, James M O'Reilly, Microwave spectrum, dipole moment, and internal barrier of 2-fluoropropene☆ Journal of Molecular Spectroscopy. ,vol. 3, pp. 536- 547 ,(1959) , 10.1016/0022-2852(59)90046-3