Microwave Spectrum and Barrier to Internal Rotation ofcis‐1‐Fluoropropylene
作者： Robert A. Beaudet , E. Bright Wilson
DOI: 10.1063/1.1733225
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摘要: The microwave spectrum of cis CH3CF=CHF was investigated in the region 8–36 kMc. rotational constants are 17 826.09, 5656.57, and 4406.91 Mc. value inertial defect indicates a planar structure except for two methyl hydrogen atoms. barrier to internal rotation group determined be 1057±50 cal from splitting ground‐state transitions. dipole moment is 1.46 D. sharp lowering on introduction fluorine suggests direct nonbonded interaction hydrogens.
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sci-hub.se 参考文章(15)
Melvin Spencer Newman, Steric effects in organic chemistry ,(1956)
E. Bright Wilson, Chun Chia Lin, David R. Lide, Calculation of Energy Levels for Internal Torsion and Over‐All Rotation. I. CH3BF2Type Molecules The Journal of Chemical Physics. ,vol. 23, pp. 136- 142 ,(1955) , 10.1063/1.1740512
CHUN C. LIN, JEROME D. SWALEN, Internal Rotation and Microwave Spectroscopy Reviews of Modern Physics. ,vol. 31, pp. 841- 891 ,(1959) , 10.1103/REVMODPHYS.31.841
Dudley R. Herschbach, Calculation of Energy Levels for Internal Torsion and Over‐All Rotation. III The Journal of Chemical Physics. ,vol. 31, pp. 91- 108 ,(1959) , 10.1063/1.1730343
James M. O'Reilly, Louis Pierce, Microwave Spectrum, Structure, Dipole Moment, and Internal Barrier of Vinyl Silane The Journal of Chemical Physics. ,vol. 34, pp. 1176- 1181 ,(1961) , 10.1063/1.1731716
David R. Lide, Daniel Christensen, Molecular Structure of Propylene Journal of Chemical Physics. ,vol. 35, pp. 1374- 1378 ,(1961) , 10.1063/1.1732055
Dudley R. Herschbach, Lawrence C. Krisher, Microwave Spectrum of CH2DCH : CH2; Equilibrium Conformation of Propylene Journal of Chemical Physics. ,vol. 28, pp. 728- 729 ,(1958) , 10.1063/1.1744232
David R. Lide, D. E. Mann, Microwave Spectra of Molecules Exhibiting Internal Rotation. I. Propylene The Journal of Chemical Physics. ,vol. 27, pp. 868- 873 ,(1957) , 10.1063/1.1743867
K. B. McAfee, R. H. Hughes, E. Bright Wilson, A Stark‐Effect Microwave Spectrograph of High Sensitivity Review of Scientific Instruments. ,vol. 20, pp. 821- 826 ,(1949) , 10.1063/1.1741397
R. W. Kilb, Chun Chia Lin, E. B. Wilson, Calculation of Energy Levels for Internal Torsion and Over‐All Rotation. II. CH3CHO Type Molecules; Acetaldehyde Spectra The Journal of Chemical Physics. ,vol. 26, pp. 1695- 1703 ,(1957) , 10.1063/1.1743607