Negative Ions, Ozone, and Metastable Components in dc Oxygen Glow Discharge
作者： L. E. Khvorostovskaya , V. A. Yankovsky
关键词: Oxygen 、 Glow discharge 、 Reaction rate constant 、 Electron 、 Chemistry 、 Metastability 、 Ozone 、 Gas pressure 、 Analytical chemistry 、 Ion
摘要: In a dc glow discharge in oxygen, the concentrations of minor components O2(a1Δg), O2(b1 Σg), O3, O(1D), as well nagative ions and electrons have been measured. Balance equations derived which describe satisfactorily stationary these functions gas pressure current. For first time, rate constants important aeronomical reactions (a) O− + O2(a1Δg) O3 e, (b) O2− 2O2 e (c) +O measured temperature T mean energies Ei electron E6: Ka = (2.5 ± 0.5) · 10−9 (T/300)4 0.4· (Ei/0.04)−2.6 0.4 cm3/s for 385−605 K 0.10 − 0.66 eV; Kb (1.0 0.3) 10−10 (T/300)−2 0.5 (Ei/0.04)0.23 0.05 330−605 0.09 1.5 Kc Ee 0.8÷5 eV.
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sci-hub.se 参考文章(21)
T. G Slanger, G. Black, Interactions of O2 (b 1Σg+) with O(3P) and O3 Journal of Chemical Physics. ,vol. 70, pp. 3434- 3438 ,(1979) , 10.1063/1.437877
DL Baulch, RA Cox, PJ Crutzen, RF Hampson Jr, JA Kerr, J Troe, RT Watson, None, Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement I CODATA Task Group on Chemical Kinetics Journal of Physical and Chemical Reference Data. ,vol. 11, pp. 327- 496 ,(1982) , 10.1063/1.555664
S. B. Woo, S. F. Wong, Interpretation of Rate Constants Measured in Drift Tubes in Terms of Cross Sections The Journal of Chemical Physics. ,vol. 55, pp. 3531- 3541 ,(1971) , 10.1063/1.1676609
S B Woo, S P Hong, J H Whealton, Semi-empirical joint ion-neutral speed distributions in a weakly ionized gas in electric fields Journal of Physics B. ,vol. 9, pp. 2553- 2558 ,(1976) , 10.1088/0022-3700/9/14/022
B C O'Neill, J D Craggs, Collisional detachment of electrons and ion molecule reactions in oxygen Journal of Physics B. ,vol. 6, pp. 2625- 2633 ,(1973) , 10.1088/0022-3700/6/12/028
K. Mašek, L. Láska, T. Růžička, Electron collision rates in oxygen glow discharge Czechoslovak Journal of Physics. ,vol. 28, pp. 1321- 1334 ,(1978) , 10.1007/BF01599705
Kanehiro Nobata, Masashi Kando, Characteristics and contraction of oxygen glow discharge Journal of Applied Physics. ,vol. 50, pp. 3956- 3963 ,(1979) , 10.1063/1.326525
H. Sabadil, P. Bachmann, H. Kastelewicz, Reaktionskinetik der Ozonbildung in der Sauerstoffglimmentladung Contributions To Plasma Physics. ,vol. 20, pp. 283- 295 ,(1980) , 10.1002/CTPP.19800200405
L. Frommhold, Über verzögerte Elektronen in Elektronenlawinen, insbesondere in Sauerstoff und Luft, durch Bildung und Zerfall negativer Ionen (O-) Protein Science. ,vol. 12, pp. 597- 642 ,(1964) , 10.1002/PROP.19640121102
J. O. Sullivan, Peter Warneck, Reactions of 1D Oxygen Atoms. III. Ozone Formation in the 1470‐Å Photolysis of O2 The Journal of Chemical Physics. ,vol. 46, pp. 953- 959 ,(1967) , 10.1063/1.1840832