Reaction Kinetics and Chemical Quasi-Equilibria of the Ozone Synthesis in Oxygen DC Discharges
作者： H. Jacobs , F. Miethke , A. Rutscher , H.-E. Wagner
关键词:
摘要: The spatial distribution of ozone and oxygen atoms was studied along the active passive zone a dc discharge (positive column, pressure: p = (4... 10). 10 2 Pa, current: I 2... 50 mA, flow rate: F 5...100 sccm) in flowing oxygen. composition final output 02/03-mixture is controlled by relaxation processes reactor zone. It affected sensitively total number density gas temperature afterglow. Steady states meaning reversible chemical quasi-equilibria were observed analysed extensively. Within detailed kinetic model formation these equilibria can be explained quantitatively. synthesis to above all metastable O (α 1 Δg) species, which modify drastically results for basic mechanism, considering 3 P D states.
harvard.edu
sci-hub.se 参考文章(9)
M. Touzeau, G. Gousset, J. Jolly, D. Pagnon, M. Vialle, C. M. Ferreira, J. Loureiro, M. Pinheiro, P. A. Sà, Spectroscopy and Kinetics of an Oxygen Glow Discharge Nonequilibrium Processes in Partially Ionized Gases. pp. 571- 579 ,(1990) , 10.1007/978-1-4615-3780-9_47
L. E. Khvorostovskaya, V. A. Yankovsky, Negative Ions, Ozone, and Metastable Components in dc Oxygen Glow Discharge Contributions To Plasma Physics. ,vol. 31, pp. 71- 88 ,(1991) , 10.1002/CTPP.2150310109
R. Seeliger, Untersuchungen aus dem Gebiet der Gasentladungsphysik Zeitschrift für Naturforschung A. ,vol. 8, pp. 74- 79 ,(1953) , 10.1515/ZNA-1953-0116
Erwin Wrede, Konzentrationsmessungen an einatomigem Wasserstoff, Stickstoff und Sauerstoff European Physical Journal. ,vol. 54, pp. 53- 73 ,(1929) , 10.1007/BF01339805
Heinz Sabadil, Gunn‐Instabilitäten in der positiven Säule der Sauerstoff‐Entladung Contributions To Plasma Physics. ,vol. 8, pp. 299- 308 ,(1968) , 10.1002/CTPP.19680080407
A. Rutscher, H. E. Wagner, The model of macroscopic kinetics in non-equilibrium plasma chemical reactions. I: General considerations and basic relations Contributions To Plasma Physics. ,vol. 25, pp. 337- 350 ,(1985) , 10.1002/CTPP.19850250404
H. Sabadil, P. Bachmann, H. Kastelewicz, Reaktionskinetik der Ozonbildung in der Sauerstoffglimmentladung Contributions To Plasma Physics. ,vol. 20, pp. 283- 295 ,(1980) , 10.1002/CTPP.19800200405
A Rutscher, H -E Wagner, Chemical quasi-equilibria: a new concept in the description of reactive plasmas Plasma Sources Science and Technology. ,vol. 2, pp. 279- 288 ,(1993) , 10.1088/0963-0252/2/4/008
R. Seeliger, A. Wichmann, Untersuchungen über die positive Säule der Glimmentladung in Sauerstoff. I Annalen der Physik. ,vol. 444, pp. 235- 244 ,(1951) , 10.1002/ANDP.19514440504