Synthesis of Cr2AlC thin films by reactive magnetron sputtering

作者: Ranran Su , Hongliang Zhang , Xiangpeng Meng , Liqun Shi , Chaozhuo Liu

DOI: 10.1016/J.FUSENGDES.2017.04.129

关键词: OptoelectronicsSputter depositionCrystalliteThin filmImpurityDeposition (phase transition)Substrate (electronics)Phase (matter)Materials scienceSputteringMechanical engineeringGeneral Materials ScienceNuclear Energy and EngineeringCivil and Structural Engineering

摘要: Abstract Cr2AlC thin films are deposited on MgO (100) and Al2O3 (0001) substrates with reactive radio frequency (RF) magnetron sputtering for the first time. Single phase synthesized at a substrate temperature of 480 °C deposition power 70W, preferred orientation. The film is polycrystalline dense microstructure. orientation disappears AlCr2 impurity emerges as rise during deposition. When 90 W or higher, becomes totally due to C loss. stable in vacuum temperatures up 700 °C, but starts decompose into Cr7C3 800 °C.

参考文章(44)
E.I. Zamulaeva, E.A. Levashov, E.A. Skryleva, T.A. Sviridova, Ph.V. Kiryukhantsev-Korneev, Conditions for formation of MAX phase Cr2AlC in electrospark coatings deposited onto titanium alloy Surface and Coatings Technology. ,vol. 298, pp. 15- 23 ,(2016) , 10.1016/J.SURFCOAT.2016.04.058
Ranran Su, Hongliang Zhang, DJ O’Connor, Liqun Shi, Xiangpeng Meng, Haibin Zhang, None, Deposition and characterization of Ti2AlC MAX phase and Ti3AlC thin films by magnetron sputtering Materials Letters. ,vol. 179, pp. 194- 197 ,(2016) , 10.1016/J.MATLET.2016.05.086
Arni S. Ingason, Andrejs Petruhins, Johanna Rosen, Toward Structural Optimization of MAX Phases as Epitaxial Thin Films Materials research letters. ,vol. 4, pp. 152- 160 ,(2016) , 10.1080/21663831.2016.1157525
Mark D. Tucker, Per O. Å. Persson, Mathew C. Guenette, Johanna Rosén, Marcela M. M. Bilek, David R. McKenzie, Substrate orientation effects on the nucleation and growth of the Mn+1AXn phase Ti2AlC Journal of Applied Physics. ,vol. 109, pp. 014903- ,(2011) , 10.1063/1.3527960
Zongjian Feng, Peiling Ke, Aiying Wang, Preparation of Ti2AlC MAX Phase Coating by DC Magnetron Sputtering Deposition and Vacuum Heat Treatment Journal of Materials Science & Technology. ,vol. 31, pp. 1193- 1197 ,(2015) , 10.1016/J.JMST.2015.10.014
Jonathan E. Spanier, Surojit Gupta, Maher Amer, Michel W. Barsoum, Vibrational behavior of the M n + 1 A X n phases from first-order Raman scattering ( M = Ti , V , Cr , A = Si , X = C , N ) Physical Review B. ,vol. 71, pp. 012103- ,(2005) , 10.1103/PHYSREVB.71.012103
Darin J. Tallman, Elizabeth N. Hoffman, El’ad N. Caspi, Brenda L. Garcia-Diaz, Gordon Kohse, Robert L. Sindelar, Michel W. Barsoum, Effect of neutron irradiation on select MAX phases Acta Materialia. ,vol. 85, pp. 132- 143 ,(2015) , 10.1016/J.ACTAMAT.2014.10.068
V.D. Jovic, B.M. Jovic, S. Gupta, T. El-Raghy, M.W. Barsoum, Corrosion behavior of select MAX phases in NaOH, HCl and H2SO4 Corrosion Science. ,vol. 48, pp. 4274- 4282 ,(2006) , 10.1016/J.CORSCI.2006.04.005
M.W. Barsoum, T. El-Raghy, C.J. Rawn, W.D. Porter, H. Wang, E.A. Payzant, C.R. Hubbard, Thermal properties of Ti3SiC2 Journal of Physics and Chemistry of Solids. ,vol. 60, pp. 429- 439 ,(1999) , 10.1016/S0022-3697(98)00313-8
K. Katayama, H. Nagase, Y. Manabe, Y. Kodama, T. Takeishi, M. Nishikawa, Formation of graphite re-deposition layer by hydrogen RF plasma Thin Solid Films. ,vol. 457, pp. 151- 157 ,(2004) , 10.1016/J.TSF.2003.12.030