Regioselectivity Control by Added MeCN in Ru(0)-catalyzed Cross-dimerization of Internal Alkynes with Methyl Methacrylate
作者： Sayori Kiyota , Seonyoung In , Nobuyuki Komine , Masafumi Hirano
DOI: 10.1246/CL.170224
关键词: Chemistry 、 Catalysis 、 Regioselectivity 、 Organic chemistry 、 Medicinal chemistry 、 Methyl methacrylate
摘要: Ru(η6-naphthalene)(η4-1,5-COD) (1: 10 mol %) catalyzes cross-dimerization of internal alkynes 2 with methyl methacrylate (3) to give a regioisomeric mixture the dienyl ester products, RCH=CRCH=C...
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