A regioselective Ru-catalyzed alkene-alkyne coupling.
作者： Barry M. Trost , Michelle Machacek , Matthew J. Schnaderbeck
DOI: 10.1021/OL0059504
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摘要: The reaction of silylalkynes and terminal alkenes proceeds with complete control regioselectivity by the silyl substituent to give geometrically defined vinylsilanes. Since alkynes normally mixtures, protodesilylation these adducts then constitutes a regioselective addition alkenes.
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sci-hub.se 参考文章(7)
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