Optical and luminescence properties of BaBPO5 single crystal

作者: Weifeng Li , Xiqi Feng , Chengjun Duan , Jingtai Zhao , Shili Pan

DOI: 10.1088/0022-3727/38/3/005

关键词: Single crystalAbsorption spectroscopyCrystalOptoelectronicsBand gapExcited stateLuminescenceScintillationAnalytical chemistryChemistryIrradiation

摘要: X-ray excited luminescence, optical transmission and irradiation induced absorption spectra thermo-luminescence (TL) have been investigated on a BaBPO5 single crystal. A broad luminescence band of the host is found when by x-radiation, it can be decomposed into two Gaussian components, which are identified presence defect energy levels in gap. Four bands clearly observed UV–VIS wavelength range under excitation x-rays but not UV light. The radiation damage mechanism discussed. These colour centres completely bleached annealing treatment at 150 °C. TL measurements also give proof that there exist structures crystal, corresponding trapping parameters estimated total glow peak method: E = 0.98 ± 0.02 eV S 3.4 × 1012 s−1. proved to first-order kinetics. It interesting crystals could find applications as scintillation material through control intrinsic defects

参考文章(17)
E. Messerschmid, M. Month, Theory for the fast blowup of particle bunches in accelerators Nuclear Instruments and Methods. ,vol. 141, pp. 1- 20 ,(1977) , 10.1016/0029-554X(77)90741-8
K.E. Sickafus, A.C. Larson, N. Yu, M. Nastasi, G.W. Hollenberg, F.A. Garner, R.C. Bradt, Cation disorder in high dose, neutron-irradiated spinel Journal of Nuclear Materials. ,vol. 219, pp. 128- 134 ,(1995) , 10.1016/0022-3115(94)00386-6
O.F. Schirmer, O. Thiemann, M. Wöhlecke, Defects in LiNbO3—I. experimental aspects Journal of Physics and Chemistry of Solids. ,vol. 52, pp. 185- 200 ,(1991) , 10.1016/0022-3697(91)90064-7
Shili Pan, Yicheng Wu, Peizhen Fu, Guochun Zhang, Guofu Wang, Xiangguo Guan, Chunagtian Chen, The growth of BaBPO5 crystals from Li4P2O7 flux Journal of Crystal Growth. ,vol. 236, pp. 613- 616 ,(2002) , 10.1016/S0022-0248(02)00837-0
M. Liu, A.H. Kitai, P. Mascher, Point defects and luminescence centres in zinc oxide and zinc oxide doped with manganese Journal of Luminescence. ,vol. 54, pp. 35- 42 ,(1992) , 10.1016/0022-2313(92)90047-D
G C Taylor, E Lilley, The analysis of thermoluminescent glow peaks in LiF (TLD-100) Journal of Physics D. ,vol. 11, pp. 567- 581 ,(1978) , 10.1088/0022-3727/11/4/020
Hongbin Liang, Ye Tao, Wenxuan Chen, Xin Ju, Shubin Wang, Qiang Su, The luminescent properties of lanthanide ions activated BaBPO5 in VUV–Vis range Journal of Physics and Chemistry of Solids. ,vol. 65, pp. 1071- 1076 ,(2004) , 10.1016/J.JPCS.2003.10.068
G Corradi, A Watterich, I Foldvari, R Voszka, J R Niklas, J -M Spaeth, O R Gilliam, L A Kappers, Radiation-induced intrinsic defects in TeO2 Journal of Physics: Condensed Matter. ,vol. 2, pp. 4325- 4339 ,(1990) , 10.1088/0953-8984/2/19/002
B.V.R. Chowdari, G.V. Subba Rao, C.J. Leo, XPS studies and defect structure of pure and Li-doped SrBPO5 Materials Research Bulletin. ,vol. 36, pp. 727- 736 ,(2001) , 10.1016/S0025-5408(01)00541-4