Effects of aluminum doping on lanthanum oxide gate dielectric films

作者: Hei Wong , B.L. Yang , K. Kakushima , P. Ahmet , H. Iwai

DOI: 10.1016/J.VACUUM.2011.06.023

关键词: Lanthanum oxideLanthanumGate dielectricSubstrate (electronics)Gate oxideChemical engineeringInorganic chemistryLanthanum aluminateOxideLanthanum aluminate-strontium titanate interfaceMaterials science

摘要: Abstract This work reports a novel method for improving the electrical properties of lanthanum gate oxide (La 2 O 3 ) by using aluminum doping and rapid thermal annealing (RTA) techniques. In bulk Al-doped La film together with 600 °C RTA, we found that atoms were incorporated into network was transformed aluminate complex oxide. At interface, thin Al layer formed. interfacial suppressed out-diffusion substrate Si, formation silicate silicide bonds. These effects resulted in significant reduction on interface trap densities hence leakage current.

参考文章(16)
Daniel J. Lichtenwalner, Jesse S. Jur, Angus I. Kingon, Melody P. Agustin, Yan Yang, Susanne Stemmer, Lyudmila V. Goncharova, Torgny Gustafsson, Eric Garfunkel, Lanthanum silicate gate dielectric stacks with subnanometer equivalent oxide thickness utilizing an interfacial silica consumption reaction Journal of Applied Physics. ,vol. 98, pp. 024314- ,(2005) , 10.1063/1.1988967
G. D. Wilk, R. M. Wallace, J. M. Anthony, High-κ gate dielectrics: Current status and materials properties considerations Journal of Applied Physics. ,vol. 89, pp. 5243- 5275 ,(2001) , 10.1063/1.1361065
H. Wong, H. Iwai, K. Kakushima, B. L. Yang, P. K. Chu, XPS Study of the Bonding Properties of Lanthanum Oxide/Silicon Interface with a Trace Amount of Nitrogen Incorporation Journal of The Electrochemical Society. ,vol. 157, ,(2010) , 10.1149/1.3268128
Nobuhito Kawada, Masahiko Ito, Yoji Saito, Thermal Stability of Lanthanum Oxynitride Ultrathin Films Deposited on Silicon Substrates Japanese Journal of Applied Physics. ,vol. 45, pp. 9197- 9199 ,(2006) , 10.1143/JJAP.45.9197
Yi Zhao, Masahiro Toyama, Koji Kita, Kentaro Kyuno, Akira Toriumi, Moisture-absorption-induced permittivity deterioration and surface roughness enhancement of lanthanum oxide films on silicon Applied Physics Letters. ,vol. 88, pp. 072904- ,(2006) , 10.1063/1.2174840
Banani Sen, Hei Wong, J. Molina, H. Iwai, J.A. Ng, K. Kakushima, C.K. Sarkar, Trapping characteristics of lanthanum oxide gate dielectric film explored from temperature dependent current-voltage and capacitance-voltage measurements Solid-state Electronics. ,vol. 51, pp. 475- 480 ,(2007) , 10.1016/J.SSE.2007.01.032
Hirotoshi Yamada, Takashi Shimizu, Eiichi Suzuki, Interface Reaction of a Silicon Substrate and Lanthanum Oxide Films Deposited by Metalorganic Chemical Vapor Deposition Japanese Journal of Applied Physics. ,vol. 41, pp. 368- ,(2002) , 10.1143/JJAP.41.L368
Dan Lichtenwalner, Jesse S. Jur, Angus I. Kingon, Steven Novak, Veena Misra, Reliability and Stability Issues for Lanthanum Silicate as a High-K Dielectric Meeting Abstracts. ,vol. 3, pp. 245- 252 ,(2006) , 10.1149/1.2355716
A. A. Rastorguev, V. I. Belyi, T. P. Smirnova, L. V. Yakovkina, M. V. Zamoryanskaya, V. A. Gritsenko, Hei Wong, Luminescence of intrinsic and extrinsic defects in hafnium oxide films Physical Review B. ,vol. 76, pp. 235315- ,(2007) , 10.1103/PHYSREVB.76.235315
L. Schrottke, S. L. Lu, R. Hey, M. Giehler, H. Kostial, H. T. Grahn, Population inversion and threshold current densities: A comparison of GaAs∕(Al,Ga)As quantum-cascade structures with different barrier heights Journal of Applied Physics. ,vol. 97, pp. 123104- ,(2005) , 10.1063/1.1929863