Experimental Simulation of Electric Double Layer
作者： Masashi NAKAMURA
DOI: 10.1380/JSSSJ.24.764
关键词: Electrode 、 Adsorption 、 Electrode potential 、 Ultra-high vacuum 、 Sulfuric acid 、 Half-cell 、 Molecule 、 Analytical chemistry 、 Electrolyte 、 Chemistry
摘要: The electric double layer at electrolyte-electrode interface has been investigated by an experimental simulation under ultra high vacuum (UHV). In order to reproduce on electrode surface, water is adsorbed the surface treated with electrolyte components (HCl, Na and sulfuric acid) CO. coadsorption of molecules electronegative electropositive additives indicates existence various hydration structures or orientation surfaces. By comparing results UHV conditions those from in-situ surfaces in solution, there appears be a correlation between potential. Over-layer as well ones provides ordered disordered that determine potential values.
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