Using polypyrrole nanocomposites coated on rice husk ash for the removal of anions, heavy metals, COD from textile wastewater
作者： Neama Ahmed Sobhy Ahmed Reyad
DOI: 10.1016/J.HBRCJ.2015.08.002
关键词: Fourier transform infrared spectroscopy 、 Ferric 、 Husk 、 Polypyrrole 、 Adsorption 、 Chemical oxygen demand 、 Nuclear chemistry 、 Materials science 、 Composite material 、 Chloride 、 Batch reactor
摘要: Abstract In this study, a new application of polypyrrole (PPy) synthesized chemically in presence ferric chloride as an oxidant coated on rice husk ash (RHA) by oxidative chemical polymerization method is used, has been found to be the and water reported best solvent for pyrrole. The removal anions, heavy metals such copper, iron zinc COD (chemical oxygen demand) from textile wastewater using completely mixed batch reactor (CMBR) technique investigated when its blend nanocomposites with were used. Experiments done PPy/RHA during 30 min 5 min intervals. It observed that increasing time (5–20 min) efficiency increased but, after 20 min did not increase significantly. can concluded RHA composites does play significant role anions but considerable it causes composites. Besides, morphology was tested scanning electron microscopy (SEM) characterize surface PPy at very high magnification accelerating voltage 15 kV, structure Fourier Transform Infrared spectroscopy (FTIR) wavelength range 400–4000 cm −1 , respectively. used effective adsorbent wastewater.
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B.S. Smolyakov, A.P. Ryzhikh, R.E. Romanov, The fate of Cu, Zn, and Cd in the initial stage of water system contamination: the effect of phytoplankton activity. Journal of Hazardous Materials. ,vol. 184, pp. 819- 825 ,(2010) , 10.1016/J.JHAZMAT.2010.08.115
Mohsen Ghorbani, Hossein Eisazadeh, Reza Katal, Fixed‐bed column study of the removal of anions and heavy metals from cotton textile waste water by using polyaniline and its nanocomposite containing nanometer‐size Fe3O4 Journal of Vinyl & Additive Technology. ,vol. 16, pp. 217- 221 ,(2010) , 10.1002/VNL.20224
Eduardo HL Falcão, Walter M de Azevêdo, None, Polyaniline-poly(vinyl alcohol) composite as an optical recording material Synthetic Metals. ,vol. 128, pp. 149- 154 ,(2002) , 10.1016/S0379-6779(01)00659-2
M Karthikeyan, KK Satheeshkumar, KP Elango, None, Removal of fluoride ions from aqueous solution by conducting polypyrrole Journal of Hazardous Materials. ,vol. 167, pp. 300- 305 ,(2009) , 10.1016/J.JHAZMAT.2008.12.141
Hossein Eisazadeh, Removal of chromium from waste water using polyaniline Journal of Applied Polymer Science. ,vol. 104, pp. 1964- 1967 ,(2007) , 10.1002/APP.25904
M. Matsuguchi, J. Io, G. Sugiyama, Y. Sakai, Effect of NH3 gas on the electrical conductivity of polyaniline blend films Synthetic Metals. ,vol. 128, pp. 15- 19 ,(2002) , 10.1016/S0379-6779(01)00504-5
Shubo Deng, Renbi Bai, Removal of trivalent and hexavalent chromium with aminated polyacrylonitrile fibers: performance and mechanisms. Water Research. ,vol. 38, pp. 2424- 2432 ,(2004) , 10.1016/J.WATRES.2004.02.024
A. Ohtani, M. Abe, M. Ezoe, T. Doi, T. Miyata, A. Miyake, Synthesis and properties of high-molecular-weight soluble polyaniline and its application to the 4MB-capacity barium ferrite floppy disk's antistatic coating Synthetic Metals. ,vol. 57, pp. 3696- 3701 ,(1993) , 10.1016/0379-6779(93)90499-M
Ji-Young Kim, Kwang Heon Kim, Kwang Bum Kim, Fabrication and electrochemical properties of carbon nanotube/polypyrrole composite film electrodes with controlled pore size Journal of Power Sources. ,vol. 176, pp. 396- 402 ,(2008) , 10.1016/J.JPOWSOUR.2007.09.117
Alan G. MacDiarmid, Arthur J. Epstein, Secondary doping in polyaniline Synthetic Metals. ,vol. 69, pp. 85- 92 ,(1995) , 10.1016/0379-6779(94)02374-8