Recycling of waste PET into useful textile auxiliaries.

作者: S.R. Shukla , Ajay M. Harad , Laxmikant S. Jawale

DOI: 10.1016/J.WASMAN.2006.11.002

关键词: MonomerDepolymerizationChemistryCatalysisPolyesterReusePolyethylene terephthalateTextileSodium sulfateOrganic chemistry

摘要: Polyethylene terephthalate (PET) waste fibers were initially depolymerized using a glycolysis route in the presence of sodium sulfate as catalyst, which is commonly used chemical and ecofriendly compared to heavy metal catalysts. Good yield pure monomer bis(2-hydroxyethylene terephthalate) (BHET) was obtained. Further, attempt its reuse, purified BHET converted different fatty amide derivatives obtain quaternary ammonium compounds that have potential for use softener textile finishing process. The products characterized by infrared spectroscopy. Application these synthesized carried out on cotton fabric; they evaluated performance found give good results. chemicals during depolymerization reuse PET are inexpensive comparatively less harmful environment, thus offer advantages recycling polyester fibers.

参考文章(27)
Sandro Donnini Mancini, Maria Zanin, Optimization of Neutral Hydrolysis Reaction of Post-consumer PET for Chemical Recycling: Progress in Rubber Plastics and Recycling Technology. ,vol. 20, pp. 117- 132 ,(2004) , 10.1177/147776060402000202
K. Lacasse, Werner Baumann, Textile Chemicals: Environmental Data and Facts ,(2004)
Thomas Vickerstaff, The physical chemistry of dyeing Published for Imperial Chemical Industries limited by Oliver & Boyd. ,(1950)
Vassilis A Kosmidis, Dimitris S Achilias, George P Karayannidis, None, Poly(ethylene terephthalate) Recycling and Recovery of Pure Terephthalic Acid. Kinetics of a Phase Transfer Catalyzed Alkaline Hydrolysis Macromolecular Materials and Engineering. ,vol. 286, pp. 640- 647 ,(2001) , 10.1002/1439-2054(20011001)286:10<640::AID-MAME640>3.0.CO;2-1
Jong-Wu Chen, Leo-Wang Chen, The glycolysis of poly(ethylene terephthalate) Journal of Applied Polymer Science. ,vol. 73, pp. 35- 40 ,(1999) , 10.1002/(SICI)1097-4628(19990705)73:1<35::AID-APP4>3.0.CO;2-W
K. Troev, G. Grancharov, R. Tsevi, I. Gitsov, A novel catalyst for the glycolysis of poly(ethylene terephthalate) Journal of Applied Polymer Science. ,vol. 90, pp. 1148- 1152 ,(2003) , 10.1002/APP.12711
S Mishra, A?S Goje, Kinetic and thermodynamic study of methanolysis of poly(ethylene terephthalate) waste powder Polymer International. ,vol. 52, pp. 337- 342 ,(2003) , 10.1002/PI.1147
Cheng-Ho Chen, Chuh-Yean Chen, Yu-Wen Lo, Ching-Feng Mao, Wei-Tung Liao, Studies of glycolysis of poly(ethylene terephthalate) recycled from postconsumer soft‐drink bottles. I. Influences of glycolysis conditions Journal of Applied Polymer Science. ,vol. 80, pp. 943- 948 ,(2001) , 10.1002/APP.1174