Bromide ion quenching of micellized hydrocarbon fluorescence: a search for effects of emitter lifetime on the quenching behaviour
作者： Hugh D. Burrows , Sebastião J. Formosinho , M. Fernanda , J.R. Paiva
DOI: 10.1016/0047-2670(80)85044-1
关键词: Ovalene 、 Azulene 、 Triphenylene 、 Aromatic hydrocarbon 、 Chemistry 、 Quenching (fluorescence) 、 Photochemistry 、 Bromide 、 Perylene 、 Anthracene 、 Inorganic chemistry
摘要: Abstract A study is made of the quenching by bromide ions fluorescence aromatic hydrocarbons anthracene, azulene, naphthalene, ovalene, perylene and triphenylene solubilized in cationic micelle cetyltrimethylammonium bromide. Quenching observed with all except perylene, indicating that lifetime has little effect on behaviour. The fact even short-lived azulene S2 rules out a mechanism involving diffusion hydrocarbon from centre to micellar surface. behaviour can, however, be explained basis channel model which distorts structure produce water-filled down quencher can penetrate. Stern-Volmer plots for are non-linear, partly due concentration ion Stern layer not directly proportional total concentration. In addition, it suggested contributions both aqueous phases important.
elsevier.com
sci-hub.se 参考文章(14)
J.L. Kropp, C.C. Stanley, The temperature dependence of ovalene fluorescence Chemical Physics Letters. ,vol. 9, pp. 534- 538 ,(1971) , 10.1016/0009-2614(71)85118-7
A. Nakajima, Fluorescence spectra of anthracene and pyrene in water and in aqueous surfactant solution Journal of Luminescence. ,vol. 15, pp. 277- 282 ,(1977) , 10.1016/0022-2313(77)90027-8
M. Graetzel, J. K. Thomas, Dynamics of pyrene fluorescence quenching in aqueous ionic micellar systems. Factors affecting the permeability of micelles Journal of the American Chemical Society. ,vol. 95, pp. 6885- 6889 ,(1973) , 10.1021/JA00802A002
K. Kalyanasundaram, J. K. Thomas, Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems Journal of the American Chemical Society. ,vol. 99, pp. 2039- 2044 ,(1977) , 10.1021/JA00449A004
A. R. Watkins, Kinetics of fluorescence quenching by inorganic anions The Journal of Physical Chemistry. ,vol. 78, pp. 2555- 2558 ,(1974) , 10.1021/J100618A006
Hugh D. Burrows, Sebastiao J. Formosinho, Abilio M. da Silva, Sheena E. Carlin, The quenching of the fluorescence of aromatic hydrocarbons by tertiary derivatives of group V elements Journal of Photochemistry. ,vol. 6, pp. 317- 324 ,(1976) , 10.1016/0047-2670(76)85070-8
Larry K. Patterson, Eric Vieil, Comparison of micellar effects on singlet excited states of anthracene and perylene The Journal of Physical Chemistry. ,vol. 77, pp. 1191- 1192 ,(1973) , 10.1021/J100628A022
M.A.J. Rodgers, M.E. Da Silva E Wheeler, Fluorescence from pyrene solubilized in aqueous micelles. A model for quenching by inorganic ions Chemical Physics Letters. ,vol. 43, pp. 587- 591 ,(1976) , 10.1016/0009-2614(76)80630-6
K. Kalyanasundaram, M. Graetzel, J. K. Thomas, Electrolyte-induced phase transitions in micellar systems. Proton and carbon-13 nuclear magnetic resonance relaxation and photochemical study Journal of the American Chemical Society. ,vol. 97, pp. 3915- 3922 ,(1975) , 10.1021/JA00847A008
M.A.J. Rodgers, M.F. Da Silva E Wheeler, Quenching of fluorescence from pyrene in micellar solutions by cationic quenchers Chemical Physics Letters. ,vol. 53, pp. 165- 169 ,(1978) , 10.1016/0009-2614(78)80415-1