The miscibility of cellulose-polyethylene glycol blends
作者： Yuan-Qiang Guo , Xue-Hai Liang Lclc
DOI: 10.1080/00222349908212442
关键词: Chemical engineering 、 Fourier transform infrared spectroscopy 、 Polymer blend 、 Miscibility 、 Polymer chemistry 、 Differential scanning calorimetry 、 Cellulose 、 Crystallinity 、 Polyethylene glycol 、 Materials science 、 PEG ratio
摘要: Blends of cellulose (CELL) with polyethylene glycol (PEG) were prepared from a mixed solution in dimethyl sulfoxide (DMSO)-paraformaldehyde (PF) by coagulation nonsolvent. The state miscibility the blends obtained over composition range 95/5 to 30/70 was characterized wide-angle X-ray diffraction (WAXD) and differential scanning calorimetry (DSC). WAXD DSC results indicate that crystallinity phase transition temperature PEG within decreased increasing content CELL. analysis depression shows CELL miscible. investigation Fourier transform infrared (FTIR) spectroscopy demonstrated there strong intermolecular hydrogen bond between these two components, which perhaps intrinsic reason why exhibited high level miscibility.
harvard.edu
sci-hub.se 参考文章(8)
Yuan-Qiang Guo, Xue-Hai Liang, Phase transition properties of polyethylene glycol-cellulose blends and their miscibility in mixed solvents Journal of Macromolecular Science, Part B. ,vol. 38, pp. 449- 459 ,(1999) , 10.1080/00222349908212443
Jean-Jacques Jutier, Even Lemieux, Robert E. Prud'homme, Miscibility of polyester/nitrocellulose blends: A DSC and FTIR study Journal of Polymer Science Part B: Polymer Physics. ,vol. 26, pp. 1313- 1329 ,(1988) , 10.1002/POLB.1988.090260615
Xue-Hai Liang, Yuan-Qiang Guo, Lian-Zhen Gu, En-Yong Ding, Crystalline-Amorphous Phase Transition of Poly(ethylene Glycol)/Cellulose Blend Macromolecules. ,vol. 28, pp. 6551- 6555 ,(1995) , 10.1021/MA00123A023
E. Martuscelli, M. Pracella, Ping Yue Wang, Influence of composition and molecular mass on the morphology, crystallization and melting behaviour of poly(ethylene oxide)/poly(methyl methacrylate) blends Polymer. ,vol. 25, pp. 1097- 1106 ,(1984) , 10.1016/0032-3861(84)90346-X
Yuan Qiang Guo, En Yong Ding, Lian Zhen Gu, Xue Hai Liang, Phase change behavior of polyethylene glycol in blends with cellulose Journal of Macromolecular Science, Part B. ,vol. 34, pp. 239- 248 ,(1995) , 10.1080/00222349508215532
Yoshiyuki Nishio, Tatsuo Haratani, Toshisada Takahashi, R. St. John Manley, Cellulose/poly(vinyl alcohol) blends: an estimation of thermodynamic polymer−polymer interaction by melting point depression analysis Macromolecules. ,vol. 22, pp. 2547- 2549 ,(1989) , 10.1021/MA00195A097
T. Nishi, T. T. Wang, Melting Point Depression and Kinetic Effects of Cooling on Crystallization in Poly(vinylidene fluoride)-Poly(methyl methacrylate) Mixtures Macromolecules. ,vol. 8, pp. 909- 915 ,(1975) , 10.1021/MA60048A040
Norman A. LeBel, Andrew. DeBoer, Stereochemistry of the free-radical addition of thiolacetic acid to 2-chloro-4-tert-butylcyclohexene Journal of the American Chemical Society. ,vol. 89, pp. 2784- 2785 ,(1967) , 10.1021/JA00987A079