Systematic Inflation of Buckminsterfillerene C60: Synthesis of Diphenyl Fulleroids C61 to C66

作者: T. SuzuKI , Q. LI , K. C. KHEMANI , F. WUDL , O. ALMARSSON

DOI: 10.1126/SCIENCE.254.5035.1186

关键词: InflationOrganic chemistryDivalentComputational chemistryFullereneCarbonMoleculeChemistry

摘要: The synthesis of a new family spheroidal carbon molecules derived from the fullerenes is described. fulleroids are produced by incremental addition divalent equivalent that has two phenyl (Ph) rings to fullerene C60. Ph2C61, Ph4C62, Ph6C63, Ph8C64, Ph10C65, and Ph12C66 have been prepared characterized.

参考文章(16)
C. S. Yannoni, R. D. Johnson, G. Meijer, D. S. Bethune, J. R. Salem, Carbon-13 NMR study of the C60 cluster in the solid state: molecular motion and carbon chemical shift anisotropy The Journal of Physical Chemistry. ,vol. 95, pp. 9- 10 ,(1991) , 10.1021/J100154A005
J. M. HAWKINS, A. MEYER, T. A. LEWIS, S. LOREN, F. J. HOLLANDER, Crystal structure of osmylated c60: confirmation of the soccer ball framework. Science. ,vol. 252, pp. 312- 313 ,(1991) , 10.1126/SCIENCE.252.5003.312
F. DIEDERICH, R. ETTL, Y. RUBIN, R. L. WHETTEN, R. BECK, M. ALVAREZ, S. ANZ, D. SENSHARMA, F. WUDL, K. C. KHEMANI, A. KOCH, The Higher Fullerenes: Isolation and Characterization of C76, C84, C90, C94, and C70O, an Oxide of D5h-C70. Science. ,vol. 252, pp. 548- 551 ,(1991) , 10.1126/SCIENCE.252.5005.548
P. J. Fagan, J. C. Calabrese, B. Malone, The Chemical Nature of Buckminsterfullerene (C60) and the Characterization of a Platinum Derivative Science. ,vol. 252, pp. 1160- 1161 ,(1991) , 10.1126/SCIENCE.252.5009.1160
P. M. Allemand, A. Koch, Fred Wudl, Y. Rubin, F. Diederich, M. M. Alvarez, S. J. Anz, R. L. Whetten, Two different fullerenes have the same cyclic voltammetry Journal of the American Chemical Society. ,vol. 113, pp. 1050- 1051 ,(1991) , 10.1021/JA00003A053
L. S. Sunderlin, Jose A. Paulino, Jason Chow, Bart Kahr, Dor Ben-Amotz, Robert R. Squires, Gas-phase reactivity of fullerene anions Journal of the American Chemical Society. ,vol. 113, pp. 5489- 5490 ,(1991) , 10.1021/JA00014A070
R. C. Haddon, A. F. Hebard, M. J. Rosseinsky, D. W. Murphy, S. J. Duclos, K. B. Lyons, B. Miller, J. M. Rosamilia, R. M. Fleming, A. R. Kortan, S. H. Glarum, A. V. Makhija, A. J. Muller, R. H. Eick, S. M. Zahurak, R. Tycko, G. Dabbagh, F. A. Thiel, Conducting films of C60 and C70 by alkali-metal doping Nature. ,vol. 350, pp. 320- 322 ,(1991) , 10.1038/350320A0
Joseph W. Bausch, G. K. Surya Prakash, George A. Olah, Doris S. Tse, Donald C. Lorents, Young K. Bae, Ripudaman Malhotra, Considered novel aromatic systems. 11. Diamagnetic polyanions of the C60 and C70 fullerenes: preparation, 13C and 7Li NMR spectroscopic observation, and alkylation with methyl iodide to polymethylated fullerenes Journal of the American Chemical Society. ,vol. 113, pp. 3205- 3206 ,(1991) , 10.1021/JA00008A077
Joe M. Wood, Bart Kahr, Steven H. Hoke, Lindy Dejarme, R. Graham Cooks, Dor Ben-Amotz, Oxygen and methylene adducts of C60 and C70 Journal of the American Chemical Society. ,vol. 113, pp. 5907- 5908 ,(1991) , 10.1021/JA00015A080