New biosensing platforms based on the layer-by-layer self-assembling of polyelectrolytes on Nafion/carbon nanotubes-coated glassy carbon electrodes.
作者： Gustavo A. Rivas , Silvia A. Miscoria , Jacques Desbrieres , Gustavo D. Barrera
DOI: 10.1016/J.TALANTA.2006.03.056
关键词: Carbon nanotube 、 Glucose oxidase 、 Nafion 、 Chemistry 、 Glassy carbon 、 Chemical engineering 、 Polyelectrolyte 、 Ascorbic acid 、 Carbon 、 Organic chemistry 、 Biosensor
摘要: Abstract We are proposing for the first time use of a Nafion/multi-walled carbon nanotubes dispersion deposited on glassy electrodes (GCE) as new platform developing enzymatic biosensors based self-assembling chitosan derivative and different oxidases. The obtained by deposition layer Nafion/multi-wall electrodes, followed adsorption polycation glucose oxidase, l -aminoacid oxidase or polyphenol polyanions biorecognition elements. optimum configuration has allowed highly sensitive (sensitivity = (0.28 ± 0.02) μA mM −1 , r = 0.997), fast (4 s in reaching maximum response), selective (0% interference ascorbic acid uric at physiological levels) quantification 0.700 V with detection limits 0.035 0.107 mM, respectively. repetitivity 10 measurements was 5.5%, while reproducibility 8.4% eight electrodes. potentiality clearly demonstrated using nanotubes/Nafion oxidase. Therefore, we here, that combines advantages nanostructured materials those layer-by-layer polyelectrolytes, opens doors to exciting possibilities development affinity transdution modes.
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sci-hub.se 参考文章(23)
Kuanping Gong, Yu Dong, Shaoxiang Xiong, Yi Chen, Lanqun Mao, Novel electrochemical method for sensitive determination of homocysteine with carbon nanotube-based electrodes Biosensors and Bioelectronics. ,vol. 20, pp. 253- 259 ,(2004) , 10.1016/J.BIOS.2004.01.014
Gregory G. Wildgoose, Craig E. Banks, Henry C. Leventis, Richard G. Compton, Chemically Modified Carbon Nanotubes for Use in Electroanalysis Mikrochimica Acta. ,vol. 152, pp. 187- 214 ,(2006) , 10.1007/S00604-005-0449-X
Elena Domínguez, Óscar Rincón, Arántzazu Narváez, Electrochemical DNA Sensors Based on Enzyme Dendritic Architectures: an Approach for Enhanced Sensitivity Analytical Chemistry. ,vol. 76, pp. 3132- 3138 ,(2004) , 10.1021/AC0499672
Jianxiu Wang, Meixian Li, Zujin Shi, Nanqiang Li, Zhennan Gu, None, Electrocatalytic oxidation of 3,4-dihydroxyphenylacetic acid at a glassy carbon electrode modified with single-wall carbon nanotubes Electrochimica Acta. ,vol. 47, pp. 651- 657 ,(2001) , 10.1016/S0013-4686(01)00795-2
Joseph Wang, Mustafa Musameh, A Reagentless Amperometric Alcohol Biosensor Based on Carbon-Nanotube/Teflon Composite Electrodes Analytical Letters. ,vol. 36, pp. 2041- 2048 ,(2003) , 10.1081/AL-120023628
Arántzazu Narváez, Guillaume Suárez, Ionel Catalin Popescu, Ioanis Katakis, Elena Domı́nguez, Reagentless biosensors based on self-deposited redox polyelectrolyte-oxidoreductases architectures. Biosensors and Bioelectronics. ,vol. 15, pp. 43- 52 ,(2000) , 10.1016/S0956-5663(00)00049-X
M. Chicharro, E. Bermejo, M. Moreno, A. Sánchez, A. Zapardiel, G. Rivas, Adsorptive Stripping Voltammetric Determination of Amitrole at a Multi‐Wall Carbon Nanotubes Paste Electdrode Electroanalysis. ,vol. 17, pp. 476- 482 ,(2005) , 10.1002/ELAN.200403172
Manuel Chicharro, Alberto Sánchez, Esperanza Bermejo, Antonio Zapardiel, María D Rubianes, Gustavo A Rivas, None, Carbon nanotubes paste electrodes as new detectors for capillary electrophoresis Analytica Chimica Acta. ,vol. 543, pp. 84- 91 ,(2005) , 10.1016/J.ACA.2005.04.031
P.J. Britto, K.S.V. Santhanam, P.M. Ajayan, Carbon nanotube electrode for oxidation of dopamine Bioelectrochemistry and Bioenergetics. ,vol. 41, pp. 121- 125 ,(1996) , 10.1016/0302-4598(96)05078-7
Xuecai Tan, Minjian Li, Peixiang Cai, Lijun Luo, Xiaoyong Zou, An amperometric cholesterol biosensor based on multiwalled carbon nanotubes and organically modified sol-gel/chitosan hybrid composite film. Analytical Biochemistry. ,vol. 337, pp. 111- 120 ,(2005) , 10.1016/J.AB.2004.10.040