Field emission properties of low-temperature, hydrothermally grown tungsten oxide.
作者： Maria Trapatseli , Dimitra Vernardou , Panagiotis Tzanetakis , Emmanuel Spanakis
DOI: 10.1021/AM200519W
关键词: Aqueous solution 、 Analytical chemistry 、 Materials science 、 Deposition (law) 、 Sodium tungstate 、 Field electron emission 、 Visible spectrum 、 Monoclinic crystal system 、 Hydrothermal circulation 、 Transmittance 、 Inorganic chemistry
摘要: Tungsten oxide layers have been prepared on conductive glass substrates using aqueous chemical growth from a sodium tungstate precursor at low-temperature hydrothermal conditions. The deposits were then tested as cold electron emitters. Traceable could be deposited only within narrow pH range of 1.5–2 time length not exceeding 4 h. Transmittance in the visible spectrum was found to decrease with deposition time. presence both monoclinic and hexagonal phases always detected. At longest times highest concentrations, morphologies comprise randomly oriented spikes or rods. overall emission performance is improve concentration. role morphology properties films discussed.
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sci-hub.se 参考文章(31)
Xu Chun Song, Yi Fan Zheng, E. Yang, Yun Wang, Large-scale hydrothermal synthesis of WO3 nanowires in the presence of K2SO4 Materials Letters. ,vol. 61, pp. 3904- 3908 ,(2007) , 10.1016/J.MATLET.2006.12.055
J. Zhou, Y. Ding, S. Z. Deng, L. Gong, N. S. Xu, Z. L. Wang, Three‐Dimensional Tungsten Oxide Nanowire Networks Advanced Materials. ,vol. 17, pp. 2107- 2110 ,(2005) , 10.1002/ADMA.200500885
Jiaguo Yu, Lifang Qi, Bei Cheng, Xiufeng Zhao, Effect of calcination temperatures on microstructures and photocatalytic activity of tungsten trioxide hollow microspheres Journal of Hazardous Materials. ,vol. 160, pp. 621- 628 ,(2008) , 10.1016/J.JHAZMAT.2008.03.047
A. V. Karabutov, A. V. Simakin, G. A. Shafeev, Enhanced field emission of self‐organized laser‐produced Si and Ni micro‐tip arrays with incorporated carbon nanotubes Surface and Interface Analysis. ,vol. 36, pp. 439- 443 ,(2004) , 10.1002/SIA.1724
P. R. Schwoebel, Surface-science aspects of vacuum microelectronics Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures. ,vol. 13, pp. 1391- 1410 ,(1995) , 10.1116/1.588219
Zhanjun Gu, Tianyou Zhai, Bifen Gao, Xiaohai Sheng, Yaobing Wang, Hongbing Fu, Ying Ma, Jiannian Yao, Controllable assembly of WO3 nanorods/nanowires into hierarchical nanostructures. Journal of Physical Chemistry B. ,vol. 110, pp. 23829- 23836 ,(2006) , 10.1021/JP065170Y
S Johnson, A Markwitz, M Rudolphi, H Baumann, SP Oei, KBK Teo, WI Milne, None, Field emission properties of self-assembled silicon nanostructures on n- and p-type silicon Applied Physics Letters. ,vol. 85, pp. 3277- 3279 ,(2004) , 10.1063/1.1804604
M.F. Daniel, B. Desbat, J.C. Lassegues, B. Gerand, M. Figlarz, Infrared and Raman study of WO3 tungsten trioxides and WO3, xH2O tungsten trioxide tydrates Journal of Solid State Chemistry. ,vol. 67, pp. 235- 247 ,(1987) , 10.1016/0022-4596(87)90359-8
E. Spanakis, J. Dialektos, E. Stratakis, V. Zorba, P. Tzanetakis, C. Fotakis, Ultraviolet laser structuring of silicon carbide for cold cathode applications Physica Status Solidi (c). ,vol. 5, pp. 3309- 3313 ,(2008) , 10.1002/PSSC.200779503
Michael Breedon, Paul Spizzirri, Matthew Taylor, Johan du Plessis, Dougal McCulloch, Jianmin Zhu, Leshu Yu, Zheng Hu, Colin Rix, Wojtek Wlodarski, Kourosh Kalantar-zadeh, Synthesis of Nanostructured Tungsten Oxide Thin Films: A Simple, Controllable, Inexpensive, Aqueous Sol−Gel Method Crystal Growth & Design. ,vol. 10, pp. 430- 439 ,(2010) , 10.1021/CG9010295