Structural features of dioxane lignin from Eucalyptus globulus and their relationship with the pulp yield of contrasting genotypes
作者： María Graciela Aguayo , José Ruiz , Marcela Norambuena , Regis Teixeira Mendonça
DOI: 10.4067/S0718-221X2015005000055
关键词: Pulp and paper industry 、 Pulp (paper) 、 Kraft paper 、 Lignin 、 Kraft process 、 Kappa number 、 Eucalyptus globulus 、 Materials science 、 Chemical structure 、 Pulpwood
摘要: The chemical structure of dioxane lignins isolated from two groups Eucalyptus globulus genotypes with contrasting pulpwood characteristics were evaluated. Six selected and separated in (G1 G2) based on differences wood density, pulp yield characteristics. Lignin was both milled kraft pulps produced at kappa number 16, characterized by different techniques such as FTIR, elemental analysis, molar mass distribution 31P NMR spectroscopy. From the evaluated, some determined more relevant, syringyl (S) guaiacyl (G) amounts, S/G ratio condensed biphenyl units, correlated yield. High correlations found between units (R2 = 0,69), syringyl/guaicyl 0,88). 5-5 presented a negative correlation 0,76). information obtained explained part difference pulpability can be used for selection improvement species paper industry.
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Kenneth Sundherg, Camilla Lillandt, Bjarne Holmhom, Anna Sundheq, Determination of hemicelluloses and pectins in wood and pulp fibres by acid methanolysis and gas chromatography. Nordic Pulp & Paper Research Journal. ,vol. 11, pp. 216- 219 ,(1996) , 10.3183/NPPRJ-1996-11-04-P216-219
G. Gellerstedt, J. Pranda, E.-L. Lindfors, Structural and Molecular Properties of Residual Birch Kraft Lignins Journal of Wood Chemistry and Technology. ,vol. 14, pp. 467- 482 ,(1994) , 10.1080/02773819408003108
K. K. Pandey, A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy Journal of Applied Polymer Science. ,vol. 71, pp. 1969- 1975 ,(1999) , 10.1002/(SICI)1097-4628(19990321)71:12<1969::AID-APP6>3.0.CO;2-D
Paula C. Pinto, Dmitry V. Evtuguin, Carlos Pascoal Neto, Armando J. D. Silvestre, BEHAVIOR OF EUCALYPTUS GLOBULUS LIGNIN DURING KRAFT PULPING. I. ANALYSIS BY CHEMICAL DEGRADATION METHODS Journal of Wood Chemistry and Technology. ,vol. 22, pp. 93- 108 ,(2002) , 10.1081/WCT-120013355
Hailong Li, Xin-Sheng Chai, Mengru Liu, Yonghong Deng, Novel Method for the Determination of the Methoxyl Content in Lignin by Headspace Gas Chromatography Journal of Agricultural and Food Chemistry. ,vol. 60, pp. 5307- 5310 ,(2012) , 10.1021/JF300455G
O. Faix, Classification of Lignins from Different Botanical Origins by FT-IR Spectroscopy Holzforschung. ,vol. 45, pp. 21- 28 ,(1991) , 10.1515/HFSG.1991.45.S1.21
M. Sarwar Jahan, Sung Phil Mun, Characteristics of Dioxane Lignins Isolated at Different Ages of Nalita Wood (Trema orientalis) Journal of Wood Chemistry and Technology. ,vol. 27, pp. 83- 98 ,(2007) , 10.1080/02773810701486865
Anderson Guerra, Juan Pedro Elissetche, Marcela Norambuena, Juanita Freer, Sofía Valenzuela, Jaime Rodríguez, Claudio Balocchi, Influence of Lignin Structural Features on Eucalyptus globulus Kraft Pulping Industrial & Engineering Chemistry Research. ,vol. 47, pp. 8542- 8549 ,(2008) , 10.1021/IE800320D
Alessandro Granata, Dimitris S. Argyropoulos, 2 Chloro 4,4,5,5 tetramethyl 1,3,2 dioxaphospholane, a reagent for the accurate determination of the uncondensed and condensed phenolic moieties in lignins Journal of Agricultural and Food Chemistry. ,vol. 43, pp. 1538- 1544 ,(1995) , 10.1021/JF00054A023
María Graciela Aguayo, André Ferraz, Juan Pedro Elissetche, Fernando Masarin, Regis Teixeira Mendonça, Lignin chemistry and topochemistry during kraft delignification of Eucalyptus globulus genotypes with contrasting pulpwood characteristics Holzforschung. ,vol. 68, pp. 623- 629 ,(2014) , 10.1515/HF-2013-0190