Sol-gel-derived prussian blue-silicate amperometric glucose biosensor.

作者: Subramanian Bharathi , Ovadia Lev

DOI: 10.1385/ABAB:89:2-3:209

关键词: AmperometryInorganic chemistryChemistryCatalysisBiocatalysisPrussian blueEnzyme electrodeGlucose oxidaseHydrogen peroxideBiosensor

摘要: A new type of inorganic biosensor is introduced. The sensor comprises glucose oxidase enzymes encapsulated in a sol-gel-derived Prussian blue-silicate hybrid network. Glucose detected by the biocatalytic reduction oxygen followed catalytic hydrogen peroxide Prusian blue catalyst. sol-gel silicate entails rigid encapsulating matrix, provides chemical catalysis and charge mediation from site to supporting electrode, enzyme responsible for biocatalysis. feasibility dual optical/electrochemical mode analysis also demonstrated.

参考文章(18)
W.John Albery, Philip N. Bartlett, Derek H. Craston, Amperometric enzyme electrodes: Part II. Conducting salts as electrode materials for the oxidation of glucose oxidase Journal of Electroanalytical Chemistry. ,vol. 194, pp. 223- 235 ,(1985) , 10.1016/0022-0728(85)85006-3
Miloslav Pravda, Christina M. Jungar, Emmanuel I. Iwuoha, Malcolm R. Smyth, Karel Vytras, Ari Ivaska, Evaluation of amperometric glucose biosensors based on co-immobilisation of glucose oxidase with an osmium redox polymer in electrochemically generated polyphenol films Analytica Chimica Acta. ,vol. 304, pp. 127- 138 ,(1995) , 10.1016/0003-2670(94)00616-T
O. Lev, Z. Wu, S. Bharathi, V. Glezer, A. Modestov, J. Gun, L. Rabinovich, S. Sampath, Sol−Gel Materials in Electrochemistry Chemistry of Materials. ,vol. 9, pp. 2354- 2375 ,(1997) , 10.1021/CM970367B
Jenny Gun, Ovadia Lev∗, Wiring of Glucose Oxidase to Carbon Matrices VIA Sol-Gel Derived Redox Modified Silicate Analytical Letters. ,vol. 29, pp. 1933- 1938 ,(1996) , 10.1080/00032719608000799
Paul D. Hale, Leonid I. Boguslavsky, Toru. Inagaki, Hiroko I. Karan, Hung Sui. Lee, Terje A. Skotheim, Yoshi. Okamoto, Amperometric glucose biosensors based on redox polymer-mediated electron transfer Analytical Chemistry. ,vol. 63, pp. 677- 682 ,(1991) , 10.1021/AC00007A006
Yizhu Guo, Ana R. Guadalupe, Oscar Resto, Luis F. Fonseca, S. Z. Weisz, Chemically derived prussian blue sol-gel composite thin films Chemistry of Materials. ,vol. 11, pp. 135- 140 ,(1999) , 10.1021/CM9806275
A KARYAKIN, E KARYAKINA, L GORTON, Prussian-Blue-based amperometric biosensors in flow-injection analysis Talanta. ,vol. 43, pp. 1597- 1606 ,(1996) , 10.1016/0039-9140(96)01909-1