Anionic polymerization of alkyl methacrylates using flow microreactor systems
作者： Aiichiro Nagaki , Atsuo Miyazaki , Yutaka Tomida , Jun-ichi Yoshida
DOI: 10.1016/J.CEJ.2010.07.073
关键词: Polymer chemistry 、 Monomer 、 Polymerization 、 Alkyl 、 Microreactor 、 Anionic addition polymerization 、 Living anionic polymerization 、 Molar mass distribution 、 Chemistry 、 Copolymer
摘要: Abstract Living anionic polymerization of alkyl methacrylates initiated by 1,1-diphenylhexyllithium was conducted in a flow microreactor system. A high level molecular-weight distribution control achieved under easily accessible conditions, such as at −28 °C (MMA: Mw/Mn = 1.16), 0 °C (BuMA: Mw/Mn = 1.24) and 24 °C (Bu t MA: Mw/Mn = 1.12). The molecular weight (Mn) increased with an increase the monomer/initiator ratio. subsequent reaction reactive polymer chain end second methacrylate integrated micoreactor systems led to formation block copolymer having narrow distribution.
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