Influence of oxygen vacancy on the response properties of TiO2 ultraviolet detectors

作者: Peng Gu , Xinghua Zhu , Haihua Wu , Jitao Li , Dingyu Yang

DOI: 10.1016/J.JALLCOM.2018.11.283

关键词: Binding energySubstrate (electronics)Analytical chemistryPhotoluminescenceResponsivityX-ray photoelectron spectroscopyMaterials scienceScanning electron microscopeCrystalliteSputtering

摘要: Abstract In this paper, the effect of sputtering distance between target and substrate (DTS) on structural, morphological optical properties TiO2 films were investigated. X-ray diffraction (XRD) scanning electron microscopy (SEM) revealed that crystallite size surface morphology strongly dependent DTS. The photoelectron spectroscopy (XPS) results showed obvious three peaks including C1S, Ti2p O1s could be clearly observed binding energy was 285, 458 531 eV, respectively. For each sample, four near 386, 462, 527 595 nm in photoluminescence (PL) spectra originated from intrinsic recombination, F center, F+ center electrons transferred 3d Ti3+ states to deep levels OH−, Finally, photoresponse UV detectors based analyzed detector prepared at a DTS 80 mm high responsivity 2.02 × 10−4 A/W excellent photosensitivity 32.25, also, exhibited fast response with rise time (τr) 0.98 s fall (τf) 3.14 s.

参考文章(37)
Zohra N Kayani, Tosif Afzal, Saira Riaz, Shahzad Naseem, None, Optical and structural properties of thin films of ZnO at elevated temperature Journal of Alloys and Compounds. ,vol. 606, pp. 177- 181 ,(2014) , 10.1016/J.JALLCOM.2014.04.039
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Pengtao Gao, L.J Meng, M.P dos Santos, V Teixeira, M Andritschky, Influence of sputtering power and the substrate–target distance on the properties of ZrO2 films prepared by RF reactive sputtering Thin Solid Films. ,vol. 377-378, pp. 557- 561 ,(2000) , 10.1016/S0040-6090(00)01291-8
M. Razeghi, A. Rogalski, Semiconductor ultraviolet detectors Journal of Applied Physics. ,vol. 79, pp. 7433- 7473 ,(1996) , 10.1063/1.362677
Q.A. Xu, J.W. Zhang, K.R. Ju, X.D. Yang, X. Hou, ZnO thin film photoconductive ultraviolet detector with fast photoresponse Journal of Crystal Growth. ,vol. 289, pp. 44- 47 ,(2006) , 10.1016/J.JCRYSGRO.2005.11.008
Ulrike Diebold, The surface science of titanium dioxide Surface Science Reports. ,vol. 48, pp. 53- 229 ,(2003) , 10.1016/S0167-5729(02)00100-0
Hiromichi Ohta, Masao Kamiya, Toshio Kamiya, Masahiro Hirano, Hideo Hosono, UV-detector based on pn-heterojunction diode composed of transparent oxide semiconductors, p-NiO/n-ZnO Thin Solid Films. ,vol. 445, pp. 317- 321 ,(2003) , 10.1016/S0040-6090(03)01178-7
Huolin Huang, Yannan Xie, Zifeng Zhang, Feng Zhang, Qiang Xu, Zhengyun Wu, Growth and fabrication of sputtered TiO2 based ultraviolet detectors Applied Surface Science. ,vol. 293, pp. 248- 254 ,(2014) , 10.1016/J.APSUSC.2013.12.142