Carbon dioxide utilization using a pretreated brine solution at normal temperature and pressure

作者: Dongwoo Kang , Hoyong Jo , Min-Gu Lee , Jinwon Park

DOI: 10.1016/J.CEJ.2015.09.043

关键词: Aqueous solutionAmbient pressureCalcium carbonateIndustrial wastewater treatmentCalciteBrineInorganic chemistryCalciumCarbon dioxideChemistry

摘要: Abstract Herein, we discuss carbon capture and utilization processes using industrial wastewater. 5, 10, 30 wt% aqueous monoethanolamine (MEA) solutions were used as the absorbent solution. A pretreated brine solution, in which contained calcium ion with concentration of 21972.64 ppm, was to supply cations. All experiments done under ambient pressure a temperature range between 298.15 K 343.15 K. 0.79, 0.34 0.19 mol CO 2 captured by 10 MEA solutions, respectively. When 100 ml added each saturated 24.65%, 36.96%, 41.65% (mol basis) converted carbonate salts fixation process. To investigate possibility recycle after precipitation step, second absorption performed. As result 0.55, 0.27, 0.16 mol Through X-ray diffraction (XRD) analysis scanning electron microscope (SEM) analysis, it proven that formation possible majority form calcite.

参考文章(28)
JF Daniel, PB John, Y Soong, PK JAMES, HH BRETT, JG WILLIAM, MM MAROTO-VALER, MA JOHN, Carbon Storage and Sequestration as Mineral Carbonates 221st American Chemical Society National Meeting. pp. 101- 117 ,(2002) , 10.1007/978-1-4615-0773-4_8
Seungmoon Lee, Thomas P. Filburn, Mac Gray, Jin-Won Park, Ho-Jun Song, Screening Test of Solid Amine Sorbents for CO2 Capture Industrial & Engineering Chemistry Research. ,vol. 47, pp. 7419- 7423 ,(2008) , 10.1021/IE8006984
J. Wang, U. Becker, Structure and carbonate orientation of vaterite (CaCO3) American Mineralogist. ,vol. 94, pp. 380- 386 ,(2009) , 10.2138/AM.2009.2939
Donald Langmuir, Stability of calcite based on aqueous solubility measurements Geochimica et Cosmochimica Acta. ,vol. 32, pp. 835- 851 ,(1968) , 10.1016/0016-7037(68)90099-9
Nichola McCann, Marcel Maeder, Moetaz Attalla, Simulation of Enthalpy and Capacity of CO2 Absorption by Aqueous Amine Systems Industrial & Engineering Chemistry Research. ,vol. 47, pp. 2002- 2009 ,(2008) , 10.1021/IE070619A
Nora H de Leeuw, Stephen C Parker, None, Surface Structure and Morphology of Calcium Carbonate Polymorphs Calcite, Aragonite, and Vaterite: An Atomistic Approach Journal of Physical Chemistry B. ,vol. 102, pp. 2914- 2922 ,(1998) , 10.1021/JP973210F
Dongwoo Kang, Sangwon Park, Hoyong Jo, Jinwon Park, Carbon fixation using calcium oxide by an aqueous approach at moderate conditions Chemical Engineering Journal. ,vol. 248, pp. 200- 207 ,(2014) , 10.1016/J.CEJ.2014.03.045
Sangwon Park, Hoyong Jo, Dongwoo Kang, Jinwon Park, A study of CO2 precipitation method considering an ionic CO2 and Ca(OH)2 slurry Energy. ,vol. 75, pp. 624- 629 ,(2014) , 10.1016/J.ENERGY.2014.08.036
Raffaella Demichelis, Paolo Raiteri, Julian D. Gale, Roberto Dovesi, A new structural model for disorder in vaterite from first-principles calculations CrystEngComm. ,vol. 14, pp. 44- 47 ,(2012) , 10.1039/C1CE05976A