SET-promoted photoaddition reactions of fullerene C60 with tertiary N-trimethylsilylmethyl substituted α-aminonitriles. Approach to the synthesis of fulleropyrrolidine nitriles

作者: Suk Hyun Lim , Dae Won Cho , Jungkweon Choi , Hyunjun An , Jun Ho Shim

DOI: 10.1016/J.TET.2017.08.057

关键词: ChemistryCycloadditionPyrrolidineAzomethine ylideYlidePhotochemistryArylTrimethylsilylDeprotonationMedicinal chemistryHydrogen atom abstraction

摘要: … Especially interesting in this regard are fulleropyrrolidines in which the fullerene ring system … of thermally promoted 1,3-dipolar cycloaddition reactions of fullerene C 60 with azomethine …

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