Recent Advances in Radical C-H Activation/Radical Cross-Coupling.
作者： Hong Yi , Guoting Zhang , Huamin Wang , Zhiyuan Huang , Jue Wang
DOI: 10.1021/ACS.CHEMREV.6B00620
关键词: Chemistry 、 Transition metal 、 Nucleophile 、 Radical 、 Polymer chemistry 、 Photochemistry 、 Catalysis 、 Photocatalysis
摘要: Research and industrial interest in radical C–H activation/radical cross-coupling chemistry has continuously grown over the past few decades. These reactions offer fascinating and unconventional approaches toward connecting molecular fragments with high atom-and step-economy that are often complementary to traditional methods. Success in this area of research was made possible through the development of photocatalysis and first-row transition metal catalysis along with the use of peroxides as radical initiators. This Review …
acs.org
cheric.org参考文章(313)
Guobing Yan, Arun Jyoti Borah, Lianggui Wang, Zhangjin Pan, Shuangshuang Chen, Xuqian Shen, Xiangmei Wu, α-Arylchalcogenation of acetone with diaryl dichalcogenide via metal-free oxidative C(sp3)–H bond functionalization Tetrahedron Letters. ,vol. 56, pp. 4305- 4307 ,(2015) , 10.1016/J.TETLET.2015.05.059
Ben Niu, Wannian Zhao, Yingcai Ding, Zhaogang Bian, Charles U. Pittman, Aihua Zhou, Haibo Ge, Regioselective Cross-Couplings of Coumarins and Flavones with Ethers via C(sp3)–H Functionalization Journal of Organic Chemistry. ,vol. 80, pp. 7251- 7257 ,(2015) , 10.1021/ACS.JOC.5B00800
The Mizoroki–Heck Reaction John Wiley & Sons, Ltd. ,(2009) , 10.1002/9780470716076
Hui-Ting Zeng, Jing-Mei Huang, Copper-Catalyzed Ligand-Free Amidation of Benzylic Hydrocarbons and Inactive Aliphatic Alkanes. Organic Letters. ,vol. 17, pp. 4276- 4279 ,(2015) , 10.1021/ACS.ORGLETT.5B02063
Leiyang Lv, Hui Xi, Xiaohui Bai, Zhiping Li, Iron-Catalyzed Convergent Radical Cyclization of Aldehydes with Two Alkenes to 3,4-Dihydropyrans. Organic Letters. ,vol. 17, pp. 4324- 4327 ,(2015) , 10.1021/ACS.ORGLETT.5B02138
Shi-Liu Zhou, Li-Na Guo, Xin-Hua Duan, Copper‐Catalyzed Regioselective Cross‐Dehydrogenative Coupling of Coumarins with Benzylic Csp3–H Bonds European Journal of Organic Chemistry. ,vol. 2014, pp. 8094- 8100 ,(2014) , 10.1002/EJOC.201403068
Yu Liu, Jia-Ling Zhang, Ren-Jie Song, Jin-Heng Li, Visible-Light-Facilitated 5-exo-trig Cyclization of 1,6-Dienes with Alkyl Chlorides: Selective Scission of the C(sp3)–H Bond in Alkyl Chlorides European Journal of Organic Chemistry. ,vol. 2014, pp. 1177- 1181 ,(2014) , 10.1002/EJOC.201301849
Hong Fang, Jincan Zhao, Shengyang Ni, Haibo Mei, Jianlin Han, Yi Pan, Metal-free oxidative functionalization of a C(sp(3))-H bond adjacent to nitrogen and intramolecular aromatic cyclization for the preparation of 6-amidophenanthridines. Journal of Organic Chemistry. ,vol. 80, pp. 3151- 3158 ,(2015) , 10.1021/ACS.JOC.5B00058
Lei Fang, Liangshun Chen, Jianjun Yu, Limin Wang, Benzoyl Peroxide Promoted Radical ortho-Alkylation of Nitrogen Heteroaromatics with Simple Alkanes and Alcohols European Journal of Organic Chemistry. ,vol. 2015, pp. 1910- 1914 ,(2015) , 10.1002/EJOC.201403479
Xing-Wang Lan, Nai-Xing Wang, Wei Zhang, Jia-Long Wen, Cui-Bing Bai, Yalan Xing, Yi-He Li, Copper/Manganese Cocatalyzed Oxidative Coupling of Vinylarenes with Ketones Organic Letters. ,vol. 17, pp. 4460- 4463 ,(2015) , 10.1021/ACS.ORGLETT.5B02116