Radiation synthesis of organometallic compounds. Radiolysis of benzene solutions of Co2(CO)8
作者： Mario Castiglioni , Giuseppe Cetini , Lorenza Operti , Paolo Volpe
DOI: 10.1016/S0020-1693(00)81377-8
关键词: Inorganic chemistry 、 Group 2 organometallic chemistry 、 Cobalt 、 Metal carbonyl 、 Radiolysis 、 Hydrocarbon 、 Carbyne 、 Photochemistry 、 Chemistry 、 Benzene 、 Excited state
摘要: Abstract The radiation-induced synthesis of gdot; 2 (η -cyclohexyne)hexacarbonyl dicobalt (CoCo) and 3 (2-cyclopenten-1 methylidine)-cyclo-tris(tricarbonyl cobalt)(3CoCo) from benzene Co (CO) 8 is reported. metal carbonyl species act as traps for some the excited species.
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