Infrarotspektroskopische Untersuchungen an Metallcarbonylverbindungen, V. IR‐Spektren einiger Acetylenderivate des Kobaltcarbonyls
作者： György Bor
关键词:
摘要: Die IR-Spektren einiger Verbindungen des Typs Co2(CO)6RC2R′ (I) und Co2(CO)7(C7H8O2) (III) wurden im CO-Valenzschwingungsbereich unter verfeinerten Aufnahmebedingungen erneut untersucht. Das Auftreten von funf endstandigen CO-Banden beim Verbindungstyp I sechs CO-Absorptionen Lactonkomplex III entspricht den bekannten Strukturen.
sci-hub.se 参考文章(13)
F Albert Cotton, Andrew Liehr, Geoffrey Wilkinson, None, Spectra and structures of metal-carbon monoxide compounds—II: Manganese and rhenium decacarbonyls☆ Journal of Inorganic and Nuclear Chemistry. ,vol. 2, pp. 141- 148 ,(1956) , 10.1016/0022-1902(56)80059-6
G. Bor, Infrared spectroscopic studies on metal carbonyl compounds-III: Assignment of the totally symmetric C-O stretching bands of the metal carbonyls, with special respect to the spectra of tetracobalt-dodekacarbonyl and dicobalt-octacarbonyl Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 19, pp. 1209- 1224 ,(1963) , 10.1016/0371-1951(63)80041-7
Andrew D. Liehr, On the Use of Local Symmetry in Analyzing the Infrared Spectra of Complex Molecules The Journal of Chemical Physics. ,vol. 24, pp. 162- 163 ,(1956) , 10.1063/1.1700823
G. Bor, L. Markó, Infra-red spectrum of dicobalt octacarbonyl Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 15, pp. 747- 748 ,(1959) , 10.1016/S0371-1951(59)80369-6
M.A. El-Sayed, H.D. Kaesz, Assignment of the CO stretching absorptions in C4v metal pentacarbonyl derivatives. The method of local oscillating dipoles Journal of Molecular Spectroscopy. ,vol. 9, pp. 310- 316 ,(1962) , 10.1016/0022-2852(62)90238-2
Heinz W. Sternberg, Harold Greenfield, Robert A. Friedel, John Wotiz, Raymond Markby, Irving Wender, A NEW TYPE OF METALLO-ORGANIC COMPLEX DERIVED FROM DICOBALT OCTACARBONYL AND ACETYLENES Journal of the American Chemical Society. ,vol. 76, pp. 1457- 1458 ,(1954) , 10.1021/JA01634A103
Otto Vohler, IR-Absorptionsmessungen an verschiedenartigen Kobaltcarbonyl-Verbindungen Chemische Berichte. ,vol. 91, pp. 1161- 1164 ,(1958) , 10.1002/CBER.19580910606
Harold Greenfield, Heinz W. Sternberg, Robert A. Friedel, John H. Wotiz, Raymond Markby, Irving Wender, Acetylenic Dicobalt Hexacarbonyls. Organometallic Compounds Derived from Alkynes and Dicobalt Octacarbonyl1,2 Journal of the American Chemical Society. ,vol. 78, pp. 120- 124 ,(1956) , 10.1021/JA01582A036
Ulrich Krüerke, Walter Hübel, Über Organometall‐Komplexe, VIII. Reaktionen von Kobaltcarbonyl‐Verbindungen mit Alkinen Chemische Berichte. ,vol. 94, pp. 2829- 2856 ,(1961) , 10.1002/CBER.19610941104
L. E. Orgel, The Infrared Spectra of Substituted Metal Carbonyls Inorganic Chemistry. ,vol. 1, pp. 25- 29 ,(1962) , 10.1021/IC50001A007