Flame retardant polypropylene through the joint action of sepiolite and polyamide 6

作者: Fouad Laoutid , Olivier Persenaire , Leila Bonnaud , Philippe Dubois

DOI: 10.1016/J.POLYMDEGRADSTAB.2013.07.018

关键词: CharThermogravimetric analysisComposite materialCalorimetryThermal stabilitySepioliteMaterials sciencePolypropyleneFire retardantMaleic anhydrideMaterials ChemistryMechanics of MaterialsPolymers and PlasticsCondensed matter physics

摘要: Abstract The influence of the incorporation polyamide-6 (PA) and natural sepiolite nanoparticles on both thermal degradation fire behaviour polypropylene (PP) matrix has been investigated by thermogravimetric analysis (TGA) mass loss calorimetry. For that purpose, PP/PA blends nanocomposites thereof were prepared melt processing. TGA results evidenced use maleic anhydride grafted-polypropylene (MA-g-PP) as compatibilizer led to a significant improvement in stability under air. Such was linked formation char layer preventing thermo-oxidative PP. Interestingly, resistance this further improved adding 5 wt% leading important increase time ignition reduction peak heat release rate (pHRR) during calorimeter test.

参考文章(32)
W. Lincoln Hawkins, Polymer Degradation and Stabilization ,(1983)
R. Sonnier, L. Ferry, C. Longuet, F. Laoutid, B. Friederich, A. Laachachi, J-M. Lopez-Cuesta, Combining cone calorimeter and PCFC to determine the mode of action of flame‐retardant additives Polymers for Advanced Technologies. ,vol. 22, pp. 1091- 1099 ,(2011) , 10.1002/PAT.1989
F Laoutid, L Ferry, J.M Lopez-Cuesta, A Crespy, Red phosphorus/aluminium oxide compositions as flame retardants in recycled poly(ethylene terephthalate) Polymer Degradation and Stability. ,vol. 82, pp. 357- 363 ,(2003) , 10.1016/S0141-3910(03)00213-1
M. Herrera, G. Matuschek, A. Kettrup, Main products and kinetics of the thermal degradation of polyamides. Chemosphere. ,vol. 42, pp. 601- 607 ,(2001) , 10.1016/S0045-6535(00)00233-2
P.P. Lizymol, Sabu Thomas, Flame retardant properties of binary blends: a comparison of miscible and immiscible blends Polymer Degradation and Stability. ,vol. 57, pp. 187- 189 ,(1997) , 10.1016/S0141-3910(96)00231-5
Alberto Fina, Fabio Cuttica, Giovanni Camino, Ignition of polypropylene/montmorillonite nanocomposites Polymer Degradation and Stability. ,vol. 97, pp. 2619- 2626 ,(2012) , 10.1016/J.POLYMDEGRADSTAB.2012.07.017
Helene Pernot, Martin Baumert, François Court, Ludwik Leibler, Design and properties of co-continuous nanostructured polymers by reactive blending Nature Materials. ,vol. 1, pp. 54- 58 ,(2002) , 10.1038/NMAT711
Fouad Laoutid, Damien François, Yoann Paint, Leila Bonnaud, Philippe Dubois, Using Nanosilica to Fine-Tune Morphology and Properties of Polyamide 6/Poly(propylene) Blends Macromolecular Materials and Engineering. ,vol. 298, pp. 328- 338 ,(2013) , 10.1002/MAME.201200047
Peter Reichert, Hansjörg Nitz, Stefan Klinke, Rainer Brandsch, Ralf Thomann, Rolf Mülhaupt, Poly(propylene)/organoclay nanocomposite formation: Influence of compatibilizer functionality and organoclay modification Macromolecular Materials and Engineering. ,vol. 275, pp. 8- 17 ,(2000) , 10.1002/(SICI)1439-2054(20000201)275:1<8::AID-MAME8>3.0.CO;2-6