Flame retardancy and crack resistance of transparent intumescent fire‐resistive coatings
作者： Ling Hong , Xiaoxian Hu , Weiwei Rao , Xiaoping Zhang
DOI: 10.1002/APP.42423
关键词: Materials science 、 Fourier transform infrared spectroscopy 、 Coating 、 Intumescent 、 Nuclear magnetic resonance spectroscopy 、 Polyester 、 Char 、 Composite material 、 Polydimethylsiloxane 、 Thermogravimetric analysis
摘要: In this article, dihydroxy polydimethylsiloxane (n = 5–10) was introduced into the structure of polyphosphate (PPE) to get siloxane-modified (SiPPE). Five kinds SiPPEs with different Si contents were obtained. FTIR (Fourier Transform Infrared spectroscopy) ICP (Inductively Coupled Plasma Emission Spectroscopy), 31P NMR (Nuclear Magnetic Resonance Spectroscopy) and TGA (Thermogravimetric Analysis) used characterize composition PPE SiPPEs. Six transparent fire-resistive coatings prepared by mixing amino resin five The results fire protection test showed that both time intumescent factor char layers increased increase in content Si. demonstrated carbonaceous residue coating also regularly. hardness, flexibility, digital photos, SEM (Scanning Electronic Microscopy) other testing introduction silicon oxygen segment can effectively improve crack resistance. charcoal layer more solid than before collapse not obvious after long flame shock. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42423.
sci-hub.se 参考文章(20)
Yang Xu, Keyun Qin, Da Ruan, Jun Liu, Yang Xu, Keyun Qin, Da Ruan, Jun Liu, Concepts and Properties Lattice-Valued Logic. pp. 27- 57 ,(2003) , 10.1007/978-3-540-44847-1_2
Weiyi Xing, Ping Zhang, Lei Song, Xin Wang, Yuan Hu, Effects of alpha-zirconium phosphate on thermal degradation and flame retardancy of transparent intumescent fire protective coating Materials Research Bulletin. ,vol. 49, pp. 1- 6 ,(2014) , 10.1016/J.MATERRESBULL.2013.08.033
Xiang Hu, Guojian Wang, Yan Huang, Study on the preparation and properties of novel transparent fire-resistive coatings Journal of Coatings Technology and Research. ,vol. 10, pp. 717- 726 ,(2013) , 10.1007/S11998-013-9475-5
Chin-Lung Chiang, Ri-Cheng Chang, Yie-Chan Chiu, Thermal stability and degradation kinetics of novel organic/inorganic epoxy hybrid containing nitrogen/silicon/phosphorus by sol–gel method Thermochimica Acta. ,vol. 453, pp. 97- 104 ,(2007) , 10.1016/J.TCA.2006.11.013
Dennis Price, Kelly Pyrah, T Richard Hull, G John Milnes, W Dave Wooley, John R Ebdon, Barry J Hunt, Christopher S Konkel, Ignition temperatures and pyrolysis of a flame-retardant methyl methacrylate copolymer containing diethyl(methacryloyloxymethyl)-phosphonate units Polymer International. ,vol. 49, pp. 1164- 1168 ,(2000) , 10.1002/1097-0126(200010)49:10<1164::AID-PI513>3.0.CO;2-M
Y. W. Chen-Yang, J. R. Chuang, Y. C. Yang, C. Y. Li, Y. S. Chiu, New UV-curable cyclotriphosphazenes as fire-retardant coating materials for wood Journal of Applied Polymer Science. ,vol. 69, pp. 115- 122 ,(1998) , 10.1002/(SICI)1097-4628(19980705)69:1<115::AID-APP13>3.0.CO;2-Z
Qiang Li, Pingkai Jiang, Zhanpai Su, Ping Wei, Genglin Wang, Xiaozhen Tang, Synergistic effect of phosphorus, nitrogen, and silicon on flame-retardant properties and char yield in polypropylene Journal of Applied Polymer Science. ,vol. 96, pp. 854- 860 ,(2005) , 10.1002/APP.21522
Guojian Wang, Yan Huang, Xiang Hu, Synthesis of a novel phosphorus-containing polymer and its application in amino intumescent fire resistant coating Progress in Organic Coatings. ,vol. 76, pp. 188- 193 ,(2013) , 10.1016/J.PORGCOAT.2012.09.005
Hong-Zheng Chen, Rui-Song Xu, Mang Wang, Synthesis and photoconductivity study of phthalocyanine polymers. VI. Ethylenediamine bridged polymeric MnPc Journal of Applied Polymer Science. ,vol. 69, pp. 2609- 2613 ,(1998) , 10.1002/(SICI)1097-4628(19980926)69:13<2609::AID-APP11>3.0.CO;2-P
Ya-Ni Guo, Jin-Yang Ming, Chao-Yu Li, Jin-Jun Qiu, He-Qing Tang, Cheng-Mei Liu, Preparation and properties of transparent copolymers based on cyclotriphosphazene and styrene as potential flame-retardant optical resins Journal of Applied Polymer Science. ,vol. 121, pp. 3137- 3144 ,(2011) , 10.1002/APP.33797