Maier–Saupe nematogenic fluid interacting with an isotropic and an anisotropic Yukawa potentials: field theory description

作者: I. Kravtsiv , M. Holovko , D. di Caprio

DOI: 10.1080/00268976.2012.762615

关键词: Statistical physicsAnisotropyYukawa potentialPhysicsIsotropyDistribution functionLiquid crystalElasticity (physics)Mean field theoryField theory (psychology)Classical mechanics

摘要: We adopt a field-theoretical approach to study equilibrium properties of homogeneous Maier–Saupe nematogenic fluid interacting with an isotropic and anisotropic Yukawa potentials. In the mean field approximation, we retrieve standard theory for nematic liquid crystals. Beyond show that repulsive potential plays important role in description phase. Gaussian approximation analytical expressions correlation functions, free energy, pressure, elasticity constant are derived. establish simple condition on parameters functions thermodynamic be defined Subsequently, find corrections single-particle distribution function order parameter due fluctuations.

参考文章(29)
Keith E. Gubbins, C.G. Joslin, C. G. Gray, Theory of molecular fluids Clarendon Press. ,(1984)
Ionic Soft Matter: Modern Trends in Theory and Applications Ionic Soft Matter: Modern Trends in Theory and Applications. ,(2005) , 10.1007/1-4020-3659-0
M. S. Wertheim, Correlations in the liquid–vapor interface The Journal of Chemical Physics. ,vol. 65, pp. 2377- 2381 ,(1976) , 10.1063/1.433352
D. di Caprio, M. Holovko, Spontaneous polarization of the neutral interface for valence asymmetric coulombic systems. Journal of Physical Chemistry B. ,vol. 113, pp. 2006- 2012 ,(2009) , 10.1021/JP8086573
D. di Caprio, J. Stafiej, J. P. Badiali, A field theory study of the effect of specific interactions in ionic systems: A simple model Journal of Chemical Physics. ,vol. 108, pp. 8572- 8583 ,(1998) , 10.1063/1.476286
John C. Wheeler, David Chandler, Catastrophe in the Random‐Phase Approximation: Critique of a Theory of Phase Transitions The Journal of Chemical Physics. ,vol. 55, pp. 1645- 1654 ,(1971) , 10.1063/1.1676291
Ronald Lovett, Chung Yuan Mou, Frank P Buff, None, The structure of the liquid–vapor interface Journal of Chemical Physics. ,vol. 65, pp. 570- 572 ,(1976) , 10.1063/1.433110