Synthesis and Catalytic Applications of an Extended Range of Tethered Ruthenium(II)/η6-Arene/Diamine Complexes
作者： Roy Hodgkinson , Václav Jurčík , Antonio Zanotti-Gerosa , Hans Günter Nedden , Andrew Blackaby
DOI: 10.1021/OM500788T
关键词: Diamine 、 Steric effects 、 Organic chemistry 、 Catalysis 、 Sulfonyl 、 Chemistry 、 Chiral diamine 、 Enantiopure drug 、 Ruthenium 、 Reactivity (chemistry) 、 Polymer chemistry
摘要: A series of novel enantiopure Ru(II) complexes containing a chiral diamine and η6-arene connected by tethering group have been prepared were evaluated in the asymmetric reductions range ketones. Changes to level steric hindrance addition an electron-withdrawing functionality on sulfonyl significant effect reactivity enantioselectivity catalysts.
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