Aminolysis of [Cp*Ru(μ-OEt)] 2 (Cp* = η 5 -C 5 Me 5 ) with sulfonamides: Synthesis of neutral, zwitterionic, and anionic Cp*Ru terminal sulfonamido complexes
作者： Shin Takemoto , Yoshihiro Yumoto , Hiroyuki Matsuzaka
DOI: 10.1016/J.JORGANCHEM.2016.02.029
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摘要: Abstract The reaction of [Cp*Ru(μ-OEt)]2 (1) with sulfonamides affords terminal sulfonamido complexes via alkoxo-sulfonamido exchange and either symmetrical or unsymmetrical cleavage the dimeric structure. neutral phosphine-ligated monomeric [Cp*Ru(NHTs)(PR3)n] (R = Cy, n = 1; R = Me, n = 2) are obtained by sequential treatment 1 TsNH2 PR3 in THF. When above is conducted absence PR3, a formally zwitterionic dinuclear complex [Cp*Ru−(NHTs)(μ-κ1:η6-NHTs)Ru+Cp*] isolated. aminolysis toluene, trapping Cp*Ru+ fragment solvent molecule occurs to give fully ionic salt [Cp*Ru(η6-toluene)][Cp*Ru(NHTs)2] (4a). 16-electron anionic bis(tosylamido) 4a reacts CO CNtBu, yielding 18-electron [Cp*Ru(NHTs)(L)2] (L = CO, CNtBu) free tosylamide anion, latter which isolated form [Cp*Ru(η6-toluene)][NHTs]. Mesylamido N,N′-ditosylethylenediamido analogous have also been synthesized.
sci-hub.se 参考文章(49)
U. Koelle, J. Kossakowski, D. Grumbine, T. Don Tilley, Di‐μ‐Chloro‐Bis[(η5‐Pentamethylcyclopentadienyl) Chlororuthenium(III)], [Cp*RuCl2]2 and Di‐μ‐methoxo‐Bis(η5‐Pentamethylcyclopentadienyl)diruthenium(II), [Cp*RuOMe]2 John Wiley & Sons, Ltd. pp. 225- 228 ,(2007) , 10.1002/9780470132609.CH52
U. Koelle, R. Pasch, Hydrogen exchange reactions in the course of electrophilic addition to Cp∗Ru (exo-methylenecyclohexadienyl) complexes Inorganic Chemistry Communications. ,vol. 1, pp. 395- 397 ,(1998) , 10.1016/S1387-7003(98)00107-5
Shin Takemoto, Hidenobu Morita, Kenji Karitani, Hideki Fujiwara, Hiroyuki Matsuzaka, A Bimetallic Ru2Pt Complex Containing a Trigonal-Planar μ3-Carbido Ligand: Formation, Structure, and Reactivity Relevant to the Fischer−Tropsch Process Journal of the American Chemical Society. ,vol. 131, pp. 18026- 18027 ,(2009) , 10.1021/JA907387W
Scott E. Denmark, Stephen P. O'Connor, Scott R. Wilson, Solution and Solid-State Studies of a Chiral Zinc-Sulfonamide Complex Relevant to Enantioselective Cyclopropanations Angewandte Chemie International Edition. ,vol. 37, pp. 1149- 1151 ,(1998) , 10.1002/(SICI)1521-3773(19980504)37:8<1149::AID-ANIE1149>3.0.CO;2-F
Didier Astruc, Jean Rene Hamon, Enrique Roman, Pascal Michaud, Organometallic electron reservoirs. 5. Novel mode of carbon-hydrogen activation using dioxygen via superoxide radical anion in solution and in the solid state with C5R5FeIC6R'6. Subsequent bond formation with carbon, silicon, phosphorus, manganese, iron, chromium, and molybdenum Journal of the American Chemical Society. ,vol. 103, pp. 7502- 7514 ,(1981) , 10.1021/JA00415A018
Shigeki Kuwata, Takao Ikariya, Quest for metal/NH bifunctional bioinspired catalysis in a dinuclear platform. Dalton Transactions. ,vol. 39, pp. 2984- 2992 ,(2010) , 10.1039/B927357C
Robert E. Blake, Richard H. Heyn, T.Don Tilley, Synthesis and structure of [(η5-C5Me5Ru(μ-NHPh)]2,an electron-deficient ruthenium amide complex Polyhedron. ,vol. 11, pp. 709- 710 ,(1992) , 10.1016/S0277-5387(00)83329-X
Roy Hodgkinson, Václav Jurčík, Antonio Zanotti-Gerosa, Hans Günter Nedden, Andrew Blackaby, Guy J. Clarkson, Martin Wills, Synthesis and Catalytic Applications of an Extended Range of Tethered Ruthenium(II)/η6-Arene/Diamine Complexes Organometallics. ,vol. 33, pp. 5517- 5524 ,(2014) , 10.1021/OM500788T
Joan J. Soldevila-Barreda, Isolda Romero-Canelón, Abraha Habtemariam, Peter J. Sadler, Transfer hydrogenation catalysis in cells as a new approach to anticancer drug design Nature Communications. ,vol. 6, pp. 6582- 6582 ,(2015) , 10.1038/NCOMMS7582
Henry E. Bryndza, Lawrence K. Fong, Rocco A. Paciello, Wilson Tam, John E. Bercaw, Relative metal-hydrogen, -oxygen, -nitrogen, and -carbon bond strengths for organoruthenium and organoplatinum compounds; equilibrium studies of Cp*(PMe3)2RuX and (DPPE)MePtX systems Journal of the American Chemical Society. ,vol. 109, pp. 1444- 1456 ,(1987) , 10.1021/JA00239A026