Structure and mechanical properties of diamond-like carbon films with copper functional layer by cathode arc evaporation

作者: Bing Zhou , A.V. Rogachev , Zhubo Liu , Xiaohong Jiang , Ruiqi Shen

DOI: 10.1016/J.SURFCOAT.2012.08.024

关键词: Composite materialAnnealing (metallurgy)Diffusion layerDiamond-like carbonCarbon filmSurface layerSiliconNanotechnologyMicrostructureBilayerMaterials science

摘要: Abstract Using direct-current and pulsed cathode arc plasma technique, diamond-like carbon (DLC) bilayer films with Cu functional layer (interlayer surface layer) were prepared on silicon substrate annealed at various temperatures in vacuum. The effects of annealing temperature the structure, morphology mechanical properties investigated. results showed that changed bilayers microstructure, including size sp2 clusters thickness element distribution diffusion layer. A simple three-layer model was used to describe interdiffusion between C layers. interlayer facilitated graphitic rearrangement due weak Cu/C bonds could be more effective against graphitization. Cu/DLC DLC/Cu highly dispersed nano-agglomerates surface, particle roughness largely affected by temperature. hardness stress dependent location possessed a relatively higher lower low 100–400 °C. may interest for studying relaxation DLC can advancing development based engineering materials high properties.

参考文章(32)
A.P. Mousinho, R.D. Mansano, M.C. Salvadori, Nanostructured diamond-like carbon films characterization Journal of Alloys and Compounds. ,vol. 495, pp. 620- 624 ,(2010) , 10.1016/J.JALLCOM.2009.10.195
Zhejuan Zhang, Pingang He, Zhuo Sun, Tao Feng, Yiwei Chen, Huili Li, BengKang Tay, Growth and field emission property of coiled carbon nanostructure using copper as catalyst Applied Surface Science. ,vol. 256, pp. 4417- 4422 ,(2010) , 10.1016/J.APSUSC.2009.12.059
H.A. Castillo, E. Restrepo-Parra, P.J. Arango-Arango, Chemical and morphological difference between TiN/DLC and a-C:H/DLC grown by pulsed vacuum arc techniques Applied Surface Science. ,vol. 257, pp. 2665- 2668 ,(2011) , 10.1016/J.APSUSC.2010.10.039
A.M. Korsunsky, M.R. McGurk, S.J. Bull, T.F. Page, On the hardness of coated systems Surface & Coatings Technology. ,vol. 99, pp. 171- 183 ,(1998) , 10.1016/S0257-8972(97)00522-7
J Robertson, Diamond-like amorphous carbon Materials Science & Engineering R-reports. ,vol. 37, pp. 129- 281 ,(2002) , 10.1016/S0927-796X(02)00005-0
Jinlong Jiang, Junying Hao, Xianjuan Pang, Peng Wang, Weimin Liu, Structure and characteristics of amorphous (Ti,Si)–C:H films deposited by reactive magnetron sputtering Diamond and Related Materials. ,vol. 19, pp. 1172- 1177 ,(2010) , 10.1016/J.DIAMOND.2010.05.005
Fei Zhao, Hongxuan Li, Li Ji, Yongjun Wang, Huidi Zhou, Jianmin Chen, Ti-DLC films with superior friction performance Diamond and Related Materials. ,vol. 19, pp. 342- 349 ,(2010) , 10.1016/J.DIAMOND.2010.01.008
Neeraj Dwivedi, Sushil Kumar, Hitendra K. Malik, C. Sreekumar, Saurabh Dayal, C.M.S. Rauthan, O.S. Panwar, Investigation of properties of Cu containing DLC films produced by PECVD process Journal of Physics and Chemistry of Solids. ,vol. 73, pp. 308- 316 ,(2012) , 10.1016/J.JPCS.2011.10.019
B. Segura-Giraldo, E. Restrepo-Parra, P.J. Arango-Arango, On the influence of a TiN interlayer on DLC coatings produced by pulsed vacuum arc discharge: Compositional and morphological study Applied Surface Science. ,vol. 256, pp. 136- 141 ,(2009) , 10.1016/J.APSUSC.2009.07.094
S. Chowdhury, M.T. Laugier, I.Z. Rahman, Effects of substrate temperature on bonding structure and mechanical properties of amorphous carbon films Thin Solid Films. ,vol. 447, pp. 174- 180 ,(2004) , 10.1016/S0040-6090(03)01076-9