Micellar Counterion Binding Probed by Fluorescence Quenching of 6-methoxy-N-(3-sulfopropyl)quinolinium
作者： Tsuyoshi ASAKAWA , Hiromi KUBODE , Tadahiro OZAWA , Akio OHTA , Shigeyoshi MIYAGISHI
DOI: 10.5650/JOS.54.545
关键词: Halide 、 Aqueous solution 、 Micelle 、 Quenching (fluorescence) 、 Bromide 、 Chloride 、 Cationic polymerization 、 Chemistry 、 Monomer 、 Inorganic chemistry
摘要: The halide sensitive fluorescence probe, 6-methoxy-N-(3-sulfopropyl)quinolinium (SPQ), provides a direct approach for measurement of concentrations dissociated from the surfactant monomer and micelle. gel filtration method confirms that water-soluble SPQ probe will tend to partition in aqueous bulk phase without trapping cationic micelles. is quenched by free ions with linear Stern-Volmer relation below CMC surfactants. plot gave distinct break at owing counterion binding degree micellar (β) are generally agreement those obtained conductivity method. quenching had high sensitivities constants 125 M-1 (chloride) 223 (bromide), while it was insensitive nitrate ion. selective behavior shows bind micelles displacing bromide tetradecyltrimethylammonium increase surface lower surfactants, TTAOAc (tetradecyltrimethylammonium acetate) > TTAC chloride) TTAB bromide) TTAN nitrate).
sci-hub.st 参考文章(20)
Yizhak Marcus, Introduction to liquid state chemistry ,(1977)
Laurent Gaillon, Joël Lelièvre, René Gaboriaud, Counterion Effects in Aqueous Solutions of Cationic Surfactants: Electromotive Force Measurements and Thermodynamic Model Journal of Colloid and Interface Science. ,vol. 213, pp. 287- 297 ,(1999) , 10.1006/JCIS.1999.6141
Mikael Jansson, Roger Rymdén, Counterion binding in aqueous solutions of mixed micellar aggregates from self-diffusion measurements joint international conference on information sciences. ,vol. 119, pp. 185- 193 ,(1987) , 10.1016/0021-9797(87)90258-X
K. Kalyanasundaram, Pyrene fluorescence as a probe of fluorocarbon micelles and their mixed micelles with hydrocarbon surfactants Langmuir. ,vol. 4, pp. 942- 945 ,(1988) , 10.1021/LA00082A027
Peter Stilbs, Bjoern Lindman, Determination of organic counterion binding to micelles through Fourier transform NMR self-diffusion measurements The Journal of Physical Chemistry. ,vol. 85, pp. 2587- 2589 ,(1981) , 10.1021/J150618A002
R. Zana, Ionization of cationic micelles: Effect of the detergent structure Journal of Colloid and Interface Science. ,vol. 78, pp. 330- 337 ,(1980) , 10.1016/0021-9797(80)90571-8
R. Zana, MICROVISCOSITY OF AQUEOUS SURFACTANT MICELLES : EFFECT OF VARIOUS PARAMETERS Journal of Physical Chemistry B. ,vol. 103, pp. 9117- 9125 ,(1999) , 10.1021/JP990347S
Tsuyoshi Asakawa, Hiroki Kitano, Akio Ohta, Shigeyoshi Miyagishi, Convenient Estimation for Counterion Dissociation of Cationic Micelles Using Chloride-Sensitive Fluorescence Probe Journal of Colloid and Interface Science. ,vol. 242, pp. 284- 287 ,(2001) , 10.1006/JCIS.2001.7875
P. C. Shanks, E. I. Franses, Estimation of micellization parameters of aqueous sodium dodecyl sulfate from conductivity data The Journal of Physical Chemistry. ,vol. 96, pp. 1794- 1805 ,(1992) , 10.1021/J100183A055
Francois Quirion, Linda J. Magid, Growth and counterion binding of cetyltrimethylammonium bromide aggregates at 25.degree.C: a neutron and light scattering study The Journal of Physical Chemistry. ,vol. 90, pp. 5435- 5441 ,(1986) , 10.1021/J100412A108