Oxidation of olefines with thallium III salts—I

作者: J.B. Lee , M.J. Price

DOI: 10.1016/S0040-4020(01)98437-6

关键词: Lead(IV) acetateCyclohexeneReaction productThalliumInorganic chemistryMercury(II) acetateChemistry

摘要: Abstract The oxidation of cyclohexene with thallium III acetate has been studied under a variety conditions and compared oxidations by lead IV mercury II similar conditions. products obtained vary but include cyclohexan-1,2-diols, their mono- diacetates, cyclohex-2-enyl acetate, C-formylcyclopentane its diacetate. Lead produces mixtures, gives simple reaction product.

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