Effect of electrolyte component on the synthesis of bismuth titanate by the anodic spark conversion method

作者: Xuyun Li , Zuwei Song , Na Su

DOI: 10.1016/J.IJLEO.2017.02.035

关键词: NanoparticleAdsorptionElectrochemistryBismuthBismuth titanateElectrolyteChemical engineeringMaterials sciencePhotocatalysisAnode

摘要: Abstract Bismuth titanate nanoparticles were prepared by the anodic spark conversion route and effects of electrolyte’s constituents on electrochemical process studied. The experimental results showed that oxidation initiate bismuth to trioxide, which was further transformed into titanate. By diversifying amount NaOH H2O2 in electrolyte, phase formation, optical property photocatalytic ability titanates can be well-manipulated. Pure selinite-type Bi12TiO20 with size ca. 10 nm an electrolyte containing 0.8 M 0.4 M H2O2, exhibiting better UV–vis adsorption higher activity compared bulk one.

参考文章(20)
Fu-Hsing Lu, Chu-Tsun Wu, Chueh-Ya Hung, Barium titanate films synthesized by an anodic oxidation-based electrochemical method Surface & Coatings Technology. ,vol. 153, pp. 276- 283 ,(2002) , 10.1016/S0257-8972(01)01674-7
M. Algueró, P. Ferrer, E. Vila, J. E. Iglesias, A. Castro, Bi4Ti3O12 Ceramics from Powders Prepared by Alternative Routes: Wet No‐Coprecipitation Chemistry and Mechanochemical Activation Journal of the American Ceramic Society. ,vol. 89, pp. 3340- 3347 ,(2006) , 10.1111/J.1551-2916.2006.01234.X
Zuwei Song, Hui Dai, Bismuth Titanate films produced by the tanodic spark deposition technique Materials Letters. ,vol. 123, pp. 138- 141 ,(2014) , 10.1016/J.MATLET.2014.02.114
Dan Wang, Xintong Zhang, Panpan Sun, Shan Lu, Lingling Wang, Changhua Wang, Yichun Liu, Photoelectrochemical Water Splitting with Rutile TiO2 Nanowires Array: Synergistic Effect of Hydrogen Treatment and Surface Modification with Anatase Nanoparticles Electrochimica Acta. ,vol. 130, pp. 290- 295 ,(2014) , 10.1016/J.ELECTACTA.2014.03.024
M.G. Navarro-Rojero, J.J. Romero, F. Rubio-Marcos, J.F. Fernandez, Intermediate phases formation during the synthesis of Bi4Ti3O12 by solid state reaction Ceramics International. ,vol. 36, pp. 1319- 1325 ,(2010) , 10.1016/J.CERAMINT.2009.12.023
Yun Hou, Min Wang, Xiaohong Xu, Hong Wang, Shuxia Shang, Dong Wang, Weifeng Yao, Bi20TiO32 nanocones prepared from Bi–Ti–O mixture by metalorganic decomposition method Journal of Crystal Growth. ,vol. 240, pp. 489- 494 ,(2002) , 10.1016/S0022-0248(02)01083-7
J.P Schreckenbach, N Meyer, G Marx, B.T Lee, W.M Kriven, Strontium hafnate phases by anodic spark conversion Applied Surface Science. ,vol. 205, pp. 97- 101 ,(2003) , 10.1016/S0169-4332(02)01039-5
Pin Hao, Zhenhuan Zhao, Jian Tian, Yuanhua Sang, Guangwei Yu, Hong Liu, Shaowei Chen, Weijia Zhou, Bismuth titanate nanobelts through a low-temperature nanoscale solid-state reaction Acta Materialia. ,vol. 62, pp. 258- 266 ,(2014) , 10.1016/J.ACTAMAT.2013.10.006
Fumiaki Amano, Akira Yamakata, Kohei Nogami, Masatoshi Osawa, Bunsho Ohtani, Visible light responsive pristine metal oxide photocatalyst: enhancement of activity by crystallization under hydrothermal treatment. Journal of the American Chemical Society. ,vol. 130, pp. 17650- 17651 ,(2008) , 10.1021/JA807438Z