Synthesis and photoelectric property of N-confused porphyrins bearing an ethynylbenzoic and benzoic acid moiety
作者： Nuonuo Zhang , Jiaqi Chen , Kai Cheng , Yujiao Li , Long Wang
DOI: 10.1007/S11164-016-2803-5
关键词: Palladium 、 Mass spectrum 、 Organic chemistry 、 Photoelectric effect 、 Hydrolysis 、 Electrochemistry 、 Benzoic acid 、 Quantum chemistry 、 Moiety 、 Chemistry 、 Polymer chemistry
摘要: Two novel π-enlarged palladium N-confused porphyrins (Pd-NCPs) containing benzoic acid or 4-ethynylbenzoic moiety were synthesized by dibromination, silver metallation, Pd-catalyzed cross-coupling, and hydrolysis reaction. All compounds characterized 1H-NMR mass spectra. Optical electrochemical properties also obtained. The photovoltaic of these Pd-NCPs examined the sensitizers achieved low efficiency, which was well explained quantum chemistry calculation.
springer.com
sci-hub.se 参考文章(40)
Zhe Zeng, Bao Zhang, Chengjie Li, Xiao Peng, Xiujun Liu, Shuxian Meng, Yaqing Feng, A key point of porphyrin structure affect DSSCs performance based on porphyrin sensitizers Dyes and Pigments. ,vol. 100, pp. 278- 285 ,(2014) , 10.1016/J.DYEPIG.2013.07.037
Xuejun Zhang, Ying Zhu, Xiaobo Wu, Huipeng He, Gaolei Wang, Qiaoling Li, Meso-Schiff-base substituted porphyrin dimer dyes for dye-sensitized solar cells: synthesis, electrochemical, and photovoltaic properties Research on Chemical Intermediates. ,vol. 41, pp. 4227- 4241 ,(2015) , 10.1007/S11164-013-1525-1
Dong-Hoon Won, Motoki Toganoh, Hidemitsu Uno, Hiroyuki Furuta, Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion Dalton Transactions. pp. 6151- 6158 ,(2009) , 10.1039/B906018A
Shogo Mori, Morio Nagata, Yuki Nakahata, Kazumasa Yasuta, Ryota Goto, Mutsumi Kimura, Minoru Taya, Enhancement of Incident Photon-to-Current Conversion Efficiency for Phthalocyanine-Sensitized Solar Cells by 3D Molecular Structuralization Journal of the American Chemical Society. ,vol. 132, pp. 4054- 4055 ,(2010) , 10.1021/JA9109677
Piotr J. Chmielewski, Lechoslaw Latos-Grażyński, Krystyna Rachlewicz, Tadeusz Glowiak, Tetra‐p‐tolylporphyrin with an Inverted Pyrrole Ring: A Novel Isomer of Porphyrin Angewandte Chemie. ,vol. 33, pp. 779- 781 ,(1994) , 10.1002/ANIE.199407791
Qing Wang, Wayne M. Campbell, Edia E. Bonfantani, Kenneth W. Jolley, David L. Officer, Penny J. Walsh, Keith Gordon, Robin Humphry-Baker, Mohammad K. Nazeeruddin, Michael Grätzel, Efficient light harvesting by using green Zn-porphyrin-sensitized nanocrystalline TiO2 films. Journal of Physical Chemistry B. ,vol. 109, pp. 15397- 15409 ,(2005) , 10.1021/JP052877W
Hiromitsu Maeda, Atsuhiro Osuka, Yuichi Ishikawa, Isao Aritome, Yoshio Hisaeda, Hiroyuki Furuta, N-confused porphyrin-bearing meso-perfluorophenyl groups: a potential agent that forms stable square-planar complexes with Cu(II) and Ag(III). Organic Letters. ,vol. 5, pp. 1293- 1296 ,(2003) , 10.1021/OL034227L
Tomoya Ishizuka, Hiroki Yamasaki, Atsuhiro Osuka, Hiroyuki Furuta, Syntheses of aryl- and arylethynyl-substituted N-confused porphyrins Tetrahedron. ,vol. 63, pp. 5137- 5147 ,(2007) , 10.1016/J.TET.2007.04.007
Yongzhen Wu, Wei-Hong Zhu, Shaik M. Zakeeruddin, Michael Grätzel, Insight into D-A-π-A Structured Sensitizers: A Promising Route to Highly Efficient and Stable Dye-Sensitized Solar Cells. ACS Applied Materials & Interfaces. ,vol. 7, pp. 9307- 9318 ,(2015) , 10.1021/ACSAMI.5B02475
Simon Mathew, Aswani Yella, Peng Gao, Robin Humphry-Baker, Basile F. E. Curchod, Negar Ashari-Astani, Ivano Tavernelli, Ursula Rothlisberger, Md. Khaja Nazeeruddin, Michael Grätzel, Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers Nature Chemistry. ,vol. 6, pp. 242- 247 ,(2014) , 10.1038/NCHEM.1861