Triphasic system for direct conversion of sugars to furandicarboxylic acid
作者： Yugen Zhang , Guangshun Yi
DOI:
关键词: Chromatography 、 Chemistry 、 Phase (matter) 、 Fructose 、 Tetraethylammonium bromide 、 Third phase 、 Methyl isobutyl ketone 、 Organic chemistry
摘要: There is provided a one-pot process for the conversion of sugars to furancarboxylic acids, such as 2,5-furancarboxylic acid (FDCA), in triphasic system (e.g. water or tetraethylammonium bromide (TEAB) – methyl isobutyl ketone (MIBK) water). In this reaction setup, are first converted 5-hydroxymethylfurfural (HMF) phase. Then HMF then extracted into second phase and transferred third water. acid. The overall yields obtainable between about 78% 50% from fructose glucose, respectively. invention further relates an apparatus reaction. comprises two chambers which allow chemically separated intermediate form final product one process. according may be useful industrial fabrication.
lens.org 参考文章(9)
Martin Kröger, Ulf Prüße, Klaus‐Dieter Vorlop, A new approach for the production of 2,5-furandicarboxylic acid by in situ oxidation of 5-hydroxymethylfurfural starting from fructose Topics in Catalysis. ,vol. 13, pp. 237- 242 ,(2000) , 10.1023/A:1009017929727
Takenobu Kawano, Hirokazu Kakinuma, Hirohide Matsuhisa, Toshinari Miura, Method for producing furan-2,5-dicarboxylic acid ,(2007)
Hiroyuki Nakamura, Lifang Sun, Stephen G. Weber, Dennis P. Curran, Bruno Linclau, Ilhyong Ryu, Hiroshi Matsubara, Fluorous triphase and other multiphase systems ,(2002)
James A. Dumesic, Jean Marcel Ribeiro Gallo, David Martin Alonso, Method to convert monosaccharides to 5-(hydroxymethyl) furfural (hmf) using biomass-derived solvents ,(2013)
Marcelo L. Ribeiro, Ulf Schuchardt, Cooperative effect of cobalt acetylacetonate and silica in the catalytic cyclization and oxidation of fructose to 2,5-furandicarboxylic acid Catalysis Communications. ,vol. 4, pp. 83- 86 ,(2003) , 10.1016/S1566-7367(02)00261-3
Guangshun Yi, Siew Ping Teong, Xiukai Li, Yugen Zhang, Purification of Biomass‐Derived 5‐Hydroxymethylfurfural and Its Catalytic Conversion to 2,5‐Furandicarboxylic Acid Chemsuschem. ,vol. 7, pp. 2131- 2135 ,(2014) , 10.1002/CSSC.201402105
Siew Ping Teong, Guangshun Yi, Yugen Zhang, Hydroxymethylfurfural production from bioresources: past, present and future Green Chemistry. ,vol. 16, pp. 2015- 2026 ,(2014) , 10.1039/C3GC42018C
Yoshiyuki Kamata, Katsuyuki Naito, Masatoshi Sakurai, Recording medium, recording-medium management method, and recording-medium management system ,(2003)
Tianming Chen, Junping Zhuang, Lu Lin, Method for synthesizing 2,5-furandicarboxylic acid ,(2010)